Selective hydrogenation process and catalyst therefor
OwnerStephen Baileyinventor
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Abstract
A catalyst suitable for use in hydrogenation, especially the selective hydrogenation of acetylenic compounds to olefinic compounds, which comprises palladium supported upon an alumina support material characterised in that said catalyst further comprises a compound of a lanthanide.
Claims16
A catalyst suitable for use in the hydrogenation of a hydrogenatable organic compound which consists essentially of a palladium compound supported upon a support material characterised in that said catalyst further comprises a compound of a lanthanide.
A catalyst as claimed in any of the preceding claims wherein the catalyst is in the form of shaped particles having a minimum dimension greater than 1 mm.
A catalyst as claimed in any of the preceding claims, wherein the lanthanide compound is a compound of cerium, gadolinium or lanthanum.
A catalyst as claimed in any one of the preceding claims wherein the palladium is present at a level in the range of about 50 ppm to about 1% by weight calculated as Pd metal and the weight of the total catalyst.
A catalyst as claimed in any of the preceding claims wherein the lanthanide compound is present at a concentration of 50-5000 ppmw based on the lanthanide metal and the weight of the total catalyst.
A catalyst as claimed in any of the preceding claims wherein the atomic ratio of Pd to lanthanide metal is in the range 1:0.5-1:3.5.
A catalyst as claimed in any of the preceding claims wherein the palladium is present in the form of palladium metal.
A process for the hydrogenation of a hydrogenatable organic compound comprising the step of passing a mixture of a gaseous feed containing said hydrogenatable organic compound and hydrogen over a catalyst which consists essentially of a palladium compound supported upon a support material characterised in that said catalyst further comprises a compound of a lanthanide.
Dependencies are inferred from the claim text.