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US 2006/0217281 A1Published application
Oxidation system containing a macrocyclic metal complex, the production thereof and its use
OwnerUwe Vogt, Gunter Frankeinventors
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Abstract
Disclosed is an oxidizing system comprising a macrocyclic metal complex, an oxidizing agent and an oxidation-enhancing compound. This oxidizing system is useful under a wide variety of reaction conditions for oxidizing oxidizable substances by contacting the oxidizable substance with the specific oxidizing system. An example of a possible use is in a process for removing excess, unfixed dye from textile materials after a dyeing.
Claims38
An oxidizing system comprising the three components
- 1) a macrocyclic metal complex of the general formula (I)
- where
- Y1, Y3 and Y4 are each independently a single bond or a bridge member which contains 1, 2 or 3 carbon atoms in the bridge,
- Y2 is a bridge member having at least 1 carbon atom in the bridge,
- R is independently in each occurrence hydrogen, alkyl, cycloalkyl, cycloalkenyl, alkenyl, aryl, alkynyl, alkylaryl, halogen, alkoxy, phenoxy, CH2CF3 or CF3 or two R radicals which are bound to the same carbon atom combine to form a substituted or unsubstituted benzene, cycloalkyl or cycloalkenyl ring, the carbon atom to which the two R radicals are bound being part of the benzene, cycloalkyl or cycloalkenyl ring,
- M is a transition metal in the oxidation states I, II, III, IV, V or VI or is selected from groups 6, 7, 8, 9, 10 and 11 of the periodic table,
- Q is a counterion which balances the charge of the macrocyclic metal complex on a stoichiometric basis, and
- L is a further ligand.
- 2) an oxidizing agent, and
- 3) an oxidation-enhancing compound.
7 more elements
Dependencies are inferred from the claim text.