Cathode material and battery
AssigneeSony Corporation
InventorsMichiko Komiyama, Ken Segawa, Yuzuru Fukushima
Life of this patent
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Abstract
A cathode material capable of improving capacity and superior low temperature characteristics, and a battery using the cathode material are provided. A cathode and an anode are layered with an electrolyte layer and a separator in between. The cathode contains a complex oxide containing lithium, manganese, nickel, and cobalt; a complex oxide containing lithium and at least one of nickel and cobalt; and a complex oxide containing lithium and manganese and having a spinel structure or a phosphorus oxide containing lithium and iron at a given ratio.
Claims11
A cathode material containing a first cathode active material, a second cathode active material, and a third cathode active material,
- wherein the first cathode active material is a complex oxide containing lithium (Li), manganese (Mn), nickel (Ni), and cobalt (Co),
- the second cathode active material is a complex oxide containing lithium and at least one of nickel and cobalt,
- the third cathode active material is at least one of a complex oxide containing lithium and manganese and having a spinel structure, and a phosphorus oxide containing lithium and iron (Fe), and
- a ratio by the weight ratio of the cathode active materials is a value in the range obtained by joining each dot of A, B, C, and D expressed in Mathematical formula 1, where the first cathode active material is x, the second cathode active material is y, and the third cathode active material is z in a ternary diagram with the apexes set to each cathode active material.
- A(x, y, z)=(0.76, 0.04, 0.20) (Mathematical formula 1)
- B(x, y, z)=(0.94, 0.05, 0.01)
- C(x, y, z)=(0.05, 0.94, 0.01)
- D(x, y, z)=(0.04, 0.76, 0.20)
A battery comprising:
- a cathode;
- an anode;
- and
- an electrolyte,
- wherein the cathode contains a first cathode active material, a second cathode active material, and a third cathode active material,
- the first cathode active material is a complex oxide containing lithium (Li), manganese (Mn), nickel (Ni), and cobalt (Co),
- the second cathode active material is a complex oxide containing lithium and at least one of nickel and cobalt,
- the third cathode active material is at least one of a complex oxide containing lithium and manganese and having a spinel structure and a phosphorus oxide containing lithium and iron (Fe), and
- a ratio by the weight ratio of the cathode active materials is a value in the range obtained by joining each dot of A, B, C, and D expressed in Mathematical formula 1, where the first cathode active material is x, the second cathode active material is y, and the third cathode active material is z in a ternary diagram with the apexes set to each cathode active material.
- A(x, y, z)=(0.76, 0.04, 0.20) (Mathematical formula 1)
- B(x, y, z)=(0.94, 0.05, 0.01)
- C(x, y, z)=(0.05, 0.94, 0.01)
- D(x, y, z)=(0.04, 0.76, 0.20)
Dependencies are inferred from the claim text.