Thermoplastic polymer blends of isotactic polypropylene and alpha-olefin/propylene copolymers
AssigneeExxonMobil Chemical Patents Inc.
InventorsSudhin Datta, Avinash Gadkari, Charles Cozewith
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AssigneeExxonMobil Chemical Patents Inc.
InventorsSudhin Datta, Avinash Gadkari, Charles Cozewith
Estimating the term…
Improved thermoplastic polymer blend compositions comprising an isotactic polypropylene component and an alpha-olefin and propylene copolymer component, said copolymer comprising crystallizable alpha-olefin sequences. In a preferred embodiment, improved thermoplastic polymer blends are provided comprising from about 35% to about 85% isotactic polypropylene and from about 30% to about 70% of an ethylene and propylene copolymer, wherein said copolymer comprises isotactically crystallizable propylene sequences and is predominately propylene. The resultant blends manifest unexpected compatibility characteristics, increased tensile strength, and improved process characteristics, e.g., a single melting point.
1-30. (canceled)
A propylene polymer comprising from about 84 to about 95 wt % propylene, the remainder comprising ethylene and/or a C4+ α-olefin, the polymer having a heat of fusion <75 J/g, a MWD of from about 2 to about 3.2, a crystallinity of from about 2 to about 65%, the polymer having a Mooney Viscosity (ML 1+4@125° C.) ≦ about 38.4.
The polymer according to claim 33 having a heat of fusion ≦40 J/g.
A propylene polymer comprising from about 84 to about 95 wt % propylene, the polymer having a heat of fusion less than about 60 J/g, a crystallinity of from about 2 to about 65%, the polymer having a Mooney Viscosity (ML 1+4@125° C.) ≦ about 38.4.
A propylene ethylene polymer comprising from about 84 to about 95 wt % propylene, the polymer having a heat of fusion ≦75 J/g, a crystallinity of from about 2 to about 20%, the polymer having a Mooney Viscosity (ML 1+4@125° C.) ≦ about 38.4.
A propylene polymer comprising from about 84 to about 95 wt % propylene, the remainder comprising ethylene and/or a C4+ alpha olefin, the polymer having a heat of fusion <60 J/g, a crystallinity of from about 2 to about 20%, a MWD of from about 2.0 to about 3.2, the polymer made in a solution process in the presence of a hafnium containing catalyst composition and in the presence of a catalyst activator comprising boron, fluorine and/or aluminum.
A propylene polymer comprising from about 84 to about 95 wt % propylene, less than about 10 wt % of a diene, the remainder comprising ethylene and/or butene, the polymer having a heat of fusion <60 J/g, a crystallinity of from about 2 to about 20%, a MWD of from about 2.0 to about 3.2, the polymer having a Mooney Viscosity (ML 1+4@125° C.) ≦ about 38.4, wherein the polymer is made in a solution process with a catalyst system comprising hafnium and wherein the catalyst system further comprises an activator comprising boron, fluorine and/or aluminum.
Dependencies are inferred from the claim text.