Golf ball and thermoplastic material
AssigneeCallaway Golf Company
InventorsThomas Kennedy, Mark Binette
Life of this patent
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Abstract
Disclosed herein are a novel thermoplastic material and a golf ball utilizing the thermoplastic material. The golf ball (10) preferably comprises a core (12), a cover (16) and optionally a boundary layer (14). At least one of the core (12), cover (16) or boundary layer (14) of the golf ball (10) comprises the thermoplastic material. The thermoplastic material comprises a partially to highly neutralized blend of a copolymer, a metallocene-catalyzed alpha-olefin with a softening comonomer, and a fatty acid or fatty acid salt.
Claims25
A thermoplastic material comprising:
- a copolymer of an alpha-olefin and an alpha, beta-unsaturated carboxylic acid;
- a metallocene-catalyzed alpha-olefin with a softening comonomer;
- and
- a fatty acid or salt of a fatty acid;
- wherein the thermoplastic material is partially to highly neutralized.
A golf ball comprising:
- a core;
- a cover layer formed over the core,
- wherein at least one of the core and the cover layer comprises a blend of 1) a copolymer of an alpha-olefin and an alpha, beta-unsaturated carboxylic acid, 2) a metallocene-catalyzed alpha-olefin with a softening comonomer, and 3) a fatty acid or salt of a fatty acid,
- wherein the blend is partially to highly neutralized.
A golf ball comprising:
- a core;
- a boundary layer formed over the core;
- and
- a cover formed over the core, the cover composed of a fast chemical reaction polyurethane material formed from reactants comprising diisocyanate and a polyol;
- wherein the core or the boundary layer are composed of a thermoplastic material comprising
- a copolymer of an alpha-olefin and an alpha, beta-unsaturated carboxylic acid,
- a metallocene-catalyzed alpha-olefin with a softening comonomer,
- a fatty acid or salt of a fatty acid,
- wherein the thermoplastic material is neutralized from 50% to 100%.
A golf ball comprising:
- a core comprising a polybutadiene mixture;
- a boundary layer formed over the core, the boundary layer composed of a thermoplastic material comprising
- a copolymer of an alpha-olefin and an alpha, beta-unsaturated carboxylic acid,
- a metallocene-catalyzed alpha-olefin with a softening comonomer,
- a fatty acid or salt of a fatty acid,
- wherein the thermoplastic material is neutralized from 50% to 100%;
- and
- a cover formed over the core, the cover composed of a fast chemical reaction polyurethane material formed from reactants comprising a diisocyanate and a polyol blend, wherein the fast chemical reaction polyurethane material has a Shore D hardness ranging from 30 to 60 as measured according to ASTM-D2240, and a thickness ranging from 0.010 inch to 0.044 inch.
A golf ball comprising:
- a core composed of a thermoplastic material, the core having a diameter ranging from 1.35 inches to 1.64 inches and having a PGA compression ranging from 50 to 90;
- wherein the thermoplastic material comprises
- a copolymer of an alpha-olefin and an alpha, beta-unsaturated carboxylic acid,
- a metallocene-catalyzed alpha-olefin with a softening comonomer, and
- a fatty acid or salt of a fatty acid,
- wherein the thermoplastic material is neutralized from 50% to 100%;
- a boundary layer formed over the core, the boundary layer composed of a thermoplastic material, the boundary layer having a thickness ranging from 0.020 inch to 0.075 inch, the thermoplastic material having a Shore D hardness ranging from 50 to 70 as measured according to ASTM-D2240;
- and
- a cover formed over the boundary layer, the cover composed of a fast chemical reaction aliphatic polyurethane material formed from reactants comprising and a polyurethane prepolymer and a polyol, wherein the polyurethane material has a Shore D hardness ranging from 30 to 60 as measured according to ASTM-D2240, a thickness ranging from 0.015 inch to 0.044 inch, and an aerodynamic surface geometry thereon.
A golf ball comprising:
- a core having a diameter ranging from 1.35 inches to 1.64 inches and having a PGA compression ranging from 50 to 90, the core composed of a thermoplastic material comprising
- copolymer of an alpha-olefin and an alpha, beta-unsaturated carboxylic acid,
- an ethylene-butene, and
- a magnesium oleate,
- wherein the thermoplastic material is neutralized from 50% to 100%;
- a boundary layer formed over the core, the boundary layer composed of an ionomer material, the boundary layer having a thickness ranging from 0.020 inch to 0.075 inch, the ionomer material having a Shore D hardness ranging from 50 to 70 as measured according to ASTM-D2240;
- and
- a cover formed over the boundary layer, the cover composed of a fast chemical reaction aliphatic polyurethane material formed from reactants comprising and a polyurethane prepolymer and a polyol, wherein the polyurethane material has a Shore D hardness ranging from 30 to 60 as measured according to ASTM-D2240, a thickness ranging from 0.015 inch to 0.044 inch, and an aerodynamic surface geometry thereon.
A thermoplastic material comprising:
- 30 to 60 parts of a copolymer of an alpha-olefin and an alpha, beta-unsaturated carboxylic acid;
- 30 to 60 parts of a metallocene-catalyzed alpha-olefin with a softening comonomer;
- and
- 40 to 70 parts of a fatty acid or salt of a fatty acid;
- wherein the thermoplastic material is partially to highly neutralized.
A thermoplastic material comprising:
- 30 to 60 parts of an ethylene acrylic acid;
- 30 to 60 parts of an ethylene-octene;
- 40 to 70 parts of an oleic acid;
- 5 to 15 parts of magnesium hydroxide
- wherein the thermoplastic material is partially to highly neutralized.
A process for forming a material, the process comprising:
- blending 30 to 60 parts of a copolymer of an alpha-olefin and an alpha, beta-unsaturated carboxylic acid with 30 to 60 parts of a metallocene-catalyzed alpha-olefin with a softening comonomer to create a first mixture;
- adding 40 to 70 parts of an oleic acid to the first mixture;
- adding 5 to 15 parts of magnesium hydroxide to the first mixture;
- mixing the oleic acid and magnesium hydroxide into the first mixture to create a second mixture;
- cooling the second mixture;
- extruding the second mixture to neutralize a plurality of acid groups of the second mixture to form a neutralized mixture;
- forming an article from the neutralized mixture.
Dependencies are inferred from the claim text.