Article, ink recording medium, ink-jet recording medium and production process thereof
AssigneeCanon Kabushiki Kaisha
InventorsHisao Kamo, Masanori Ito
Life of this patent
Estimating the term…
Abstract
An article having constitution that yellowing (for example, yellowing of white portions upon storage in a resin file or the like) of the article can be continuously prevented over a long period of time even when it has a porous site composed of a pigment, such as an alumina hydrate, in an ink-receiving layer is provided. An article, an ink recording medium and an ink-jet recording medium comprising a phenolic compound having a sulfonyl group and a diffusible sulfinic acid salt, and a production process of the ink-jet recording medium are provided.
Claims11
An article comprising a phenolic compound having a sulfonyl group and a diffusible sulfinic acid salt.
An ink recording medium comprising an ink-receiving layer of a microporous structure formed on a support, wherein the ink-receiving layer has a phenolic compound having a sulfonyl group and a diffusible sulfinic acid salt.
An ink-jet recording medium comprising an ink-receiving layer of a microporous structure formed on a support, wherein the ink-receiving layer has a phenolic compound having a sulfonyl group and a sulfinic acid salt, and the surface pH and internal pH of the ink-receiving layer are each from 5.0 to 8.5.
A process for producing an ink-jet recording medium, which comprises the steps of forming an ink-receiving layer, which is a microporous substance, on a support, coating the ink-receiving layer with a coating liquid containing prescribed moles of a sulfinic compound, feeding a phenol derivative the number of moles of which is smaller than the number of moles of the sulfinic compound and causing a part of the sulfinic compound to react with the phenol derivative in the ink-receiving layer to cause both the phenolic compound having a sulfonyl group and the diffusible sulfinic acid salt to coexist.
An article comprising a microporous site containing a reaction product of a sulfinic compound with a phenol derivative, and a diffusible sulfinic compound.
An article comprising a microporous site containing at least one selected from a compound represented by a general formula (I) and a compound represented by a general formula (II), and a diffusible sulfinic compound
- wherein R1 and R2 are individually hydrogen, a substituted or unsubstituted and linear, branched or cyclic alkyl group (having 1 to 30 carbon atoms), an alkoxy group (having 1 to 20 carbon atoms), a substituted or unsubstituted aryl group (having 6 to 30 carbon atoms), a mono- or di-substituted amino group (the substituent group(s) being an alkyl, acyl or alkenyl group having 1 to 20 carbon atoms), sulfide, disulfide, an amide group, an ester group, an alkenyl group, a hydroxyl group, or a substituted or unsubstituted ureido group (having 1 to 20 carbon atoms) and may form a bis form, with the proviso that both R1 and R2 are not hydrogen at the same time, at least one of R1 and R2, which is not hydrogen, is located at an o-position, and these functional groups may have an additional substituent, R3 is a substituted or unsubstituted and saturated and unsaturated alkylene group having 1 to 30 carbon atoms, a carbonyl group or a thiocarbonyl group, and R4 is a saturated alkyl, alkoxy or alkenyl group, a substituted or unsubstituted aryl group, or a substituted or unsubstituted aryloxy, alkylamino or amino group, with the proviso that these functional groups may be substituted by a hydroxy, amino, carboxyl, alkoxy, alkenyl or alkyl group,
- wherein R1 and R2 are individually hydrogen, a substituted or unsubstituted and linear, branched or cyclic alkyl group (having 1 to 30 carbon atoms), an alkoxy group (having 1 to 20 carbon atoms), a substituted or unsubstituted aryl group (having 6 to 30 carbon atoms), a mono- or di-substituted amino group (the substituent group(s) being alkyl, acyl or alkenyl group having 1 to 20 carbon atoms), sulfide, disulfide, an amide group, an ester group, an alkoxy group, an alkenyl group, a hydroxyl group, or a substituted or unsubstituted ureido group (having 1 to 20 carbon atoms) and may form a bis form, with the proviso that both R1 and R2 are not hydrogen at the same time, at least one of R1 and R2, which is not hydrogen, is located at an o-position, and these functional groups may have an additional substituent, and R3 is a saturated alkyl, alkoxy or alkenyl group, a substituted or unsubstituted aryl group, or a substituted or unsubstituted aryloxy, alkylamino or amino group, with the proviso that these functional groups may be substituted by a hydroxy, amino, carboxyl, alkoxy, alkenyl or alkyl group.
Dependencies are inferred from the claim text.