Additive for increasing the density of a fluid for casing annulus pressure control
AssigneeM-I L.L.C.
InventorsAndrew Bradbury, Christopher Sawdon, Sonny Clary, William Reid, Tom Heinz
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AssigneeM-I L.L.C.
InventorsAndrew Bradbury, Christopher Sawdon, Sonny Clary, William Reid, Tom Heinz
Estimating the term…
A method of controlling the pressure of a casing annulus in a subterranean well that includes injecting into the casing annulus a composition including a base fluid and a polymer coated colloidal solid material. The polymer coated colloidal solid material includes: a solid particle having an weight average particle diameter (d50) of less than two microns, and a polymeric dispersing agent coated onto the surface of the solid particle during the cominution (i.e. grinding) process utilized to make the colloidal particles. The polymeric dispersing agent may be a water soluble polymer having a molecular weight of at least 2000 Daltons. The solid particulate material may be selected from materials having of specific gravity of at least 2.68 and preferably the solid particulate material may be selected from barium sulfate (barite), calcium carbonate, dolomite, ilmenite, hematite, olivine, siderite, strontium sulfate, combinations and mixtures of these and other similar solids that should be apparent to one of skill in the art.
A method of making a polymer coated colloidal solid material, the method comprising grinding a solid particulate material and a polymeric dispersing agent for a sufficient time to achieve a weight average particle diameter (d50) of less than 2 microns but not more than 5% of the d50 particles are less than 0.1 micron in diameter.
A method of making a polymer coated colloidal solid material, the method comprising grinding a solid particulate material and a polymeric dispersing agent for a sufficient time to achieve a weight average particle diameter (d50) of less than 2 microns and wherein a portion of the resulting polymer coated colloidal solid material also has a weight average particle diameter less than 2.0 microns.
A method of making a colloidal solid material, the method comprising grinding a solid particulate material and a polymeric dispersing agent for a sufficient time so that the polymeric dispersing agent is absorbed to the surface of the resulting colloidal solid particles and less than 10% of the resulting colloidal solid particles have a diameter greater than 10 microns, but not more than five percent of the particles are less than 0.1 micron in diameter.
Dependencies are inferred from the claim text.