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US 2006/0188456 A1Published application
UV-light-absorbing quaternary polysiloxanes
AssigneeEvonik Goldschmidt GmbH
InventorsMichael Ferenz, Burghard Gruening, Holger Leidreiter, Erika Messinger, Matthias Pascaly, Astrid Zuendorff
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Abstract
The invention relates to UV-light-absorbing quaternary polysiloxanes in which quaternary groups and UV-absorbing radicals can be mixed independently of one another according to the general formula (I)
Claims14
A UV-light-absorbing quaternary polysiloxane of the general formula (I)
- in which the radicals
- R1 are identical or different and are in each case alkyl radicals having 1 to 22 carbon atoms or phenyl radicals,
- R2 can in part have the meaning of the radicals R1 and the other radicals R2, independently of one another, are radicals of the formulae (Ia or Ib)
- R2=-M-S (Ia)
- or
- R2=-M-Z+A− (Ib)
- with the proviso that, in the average molecule, at least two radicals R2 are in each case a radical of the formula -M-S and -M-Z+A−,
- in which
- S is a monovalent chromophore radical responsible for the UV absorption and
- Z+ is a radical of the formula (Id)
- R6, R7 are alkyl radicals having 1 to 22 carbon atoms or alkenyl radicals having 2 to 22 carbon atoms, in which the alkyl or alkenyl radicals can have hydroxyl groups,
- R8 is
- R9 may be a monovalent hydrocarbon radical having 1 to 22 carbon atoms, or
- is a monovalent chromophore radical responsible for the UV absorption,
- x=0 to 6,
- y=0 or 1 and
- M is a divalent hydrocarbon radical having at least 4 carbon atoms, which has a hydroxyl group and which may be interrupted by one or more oxygen atoms,
- A− is an inorganic or organic anion which originates from a customary physiologically compatible acid HA,
- a independently of the others has a value of from 1 to 200 and
- b has a value of from 0 to 10.
17 more elements
Dependencies are inferred from the claim text.