Method for producing copolymers and terpolymers from olefins
OwnerKatrin Koehler, Walter Kaminsky +1inventors
InventorsKatrin Koehler, Walter Kaminsky, Andrea Esisenhardt
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Abstract
The present invention relates to a process for the preparation of co- and terpolymers from olefins having improved properties. In particular, the invention relates to the preparation of ethylene-propene copolymers (EPR), ethylene-propylene-diene terpolymers (EPDM) and further copolymers of ethylene-propene, 1-olefins and dienes having elastomeric properties which are improved by their structural makeup. In particular, this is a process for the preparation of EPR and EPDM rubbers by polymerisation of ethylene and propene, optionally ethylidenenorborne as diene at temperatures between −20 to 150° C. by means of a titanium-containing mixed catalyst and donor-stabilised aluminium compounds
Claims20
Process for the preparation of co- or terpolymers from olefins, characterised in that compounds of the general formula (I)
- in which
- X1 denotes NR, PR, O or S, optionally complex-bonded to aluminium
- X2 denotes NRR′, PRR′, OR, SR, complex-bonded to aluminium
- R1 denotes linear or branched alkylene, cycloalkylidene, alkenylene, arylene, silylene, all of which may contain hetero atoms, such as N, P, O, S, F or X1 or X2, optionally complex-bonded to aluminium
- R2, R3, independently of one another, denote linear or branched alkyl, cycloalkyl, alkenyl, aryl, alkynyl, silyl, H, F, Cl, Br, I or X2, each of which may itself be partially fluorinated or perfluorinated
- R, R′, independently of one another, denote linear or branched alkyl, cycloalkyl, alkenyl, aryl, alkynyl, silyl or H, each of which may itself be partially fluorinated or perfluorinated
- m denotes 0, 1
- n denotes 1, 2, 3, 4, 5, 6, 7;
- if n>1, R1 may, independently of one another, adopt different meanings
- o denotes 0, 1
- p, q denote 0, 1, 2
- r denotes 3-p-q,
- are used as components or cocatalysts (A) in coordination catalyst systems, where the latter in turn consist of (A), (B) a titanium- or vanadium-containing mixed catalyst and optionally (C) a support based on MgCl2 or SiO2 or SiO2 in combination with MgCl2.
Dependencies are inferred from the claim text.