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US 2006/0148647 A1Published application
Combinations of phenylsulfonylurea herbicides and safeners
AssigneeBayer CropScience AG
InventorsLothar Willms, Hermann Bieringer, Erwin Hacker, Gerhard Schnabel, Klaus Lorenz
Life of this patent
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Abstract
The invention relates to combinations of sulfonylurea herbicides (A) and their salts in which R2 is H, OH, aliphatic hydrocarbon radical or hydrocarbon-oxy radical, and R1 is an acyl radical, and the other symbols are as defined in claim 1, and safeners of type (B1) and (B2) in which the symbols are as defined in claim 1.
Claims11
A herbicide/safener combination containing
- A) at least one herbicidal active substance from the group of substituted phenylsulfonylureas of the formula (A) and salts thereof
- in which
- W is O or S,
- A is a group of the formula CR′R″, in which R′ and R″ are, independently of one another, H or (C1-C4)alkyl,
- Q is O, S or a group NR6,
- m is 0 or 1,
- n is 0, 1, 2 or 3,
- R1 is H, a hydrocarbon radical or a heterocyclic radical, each of the two last-mentioned radicals being unsubstituted or substituted,
- R2 is H, OH or an aliphatic hydrocarbon or hydrocarbon-oxy radical, each of the two last-mentioned radicals being unsubstituted or substituted,
- R3 is an acyl radical,
- R4 is halogen, CN, NO2, (C1-C4)alkyl, (C1-C4)-alkoxy, [(C1-C4)alkyl]carbonyl, [(C1-C4)alkoxy]carbonyl, each of the four last-mentioned radicals being unsubstituted or substituted,
- R5 is H, (C1-C5)alkyl or (C1-C4)alkoxy,
- R6 is H, (C1-C4)alkyl, (C3-C4)alkenyl, (C3-C4)alkynyl, each of the three last-mentioned radicals being unsubstituted or substituted by one or more radicals from the group consisting of halogen, (C1-C4)alkyl, (C1-C4)-alkoxy and (C1-C4)alkylthio, or is (C1-C4)-alkoxy or OH,
- X1, X2 are, independently of one another, H, halogen, (C1-C6)alkyl, (C2-C6)alkenyl, (C2-C6)alkynyl, (C3-C7)cycloalkyl, (C1-C6)-alkoxy, (C2-C6)alkenyloxy, (C2-C6)alkynyloxy, (C1-C6)alkylthio, mono- or di-[(C1-C4)alkyl]-amino, each of the ten last-mentioned radicals being unsubstituted or substituted by one or more radicals from the group consisting of halogen, (C1-C4)alkoxy, (C1-C4)-haloalkoxy and (C1-C4)alkylthio, and
- Z is CH, N or a group of the formula C—Ro in which Ro is halogen, cyano, (C1-C3)alkyl, (C1-C3)haloalkyl, (C1-C3)alkoxy or (C1-C3)-haloalkoxy, and
- B) at least one safener from the group of compounds of the formulae (B1) and (B2)
- in which
- X′ is hydrogen, halogen, (C1-C4)alkyl, (C1-C4)alkoxy, nitro or (C1-C4)haloalkyl,
- Z′ is OR7, SR7 or NR7R8 or is a saturated or unsaturated 3- to 7-membered heterocycle which has at least one nitrogen atom and up to 3 hetero atoms, is linked via the nitrogen atom to the carbonyl group in (B1) or (B2) and is unsubstituted or substituted by radicals from the group consisting of (C1-C4)alkyl, (C1-C4)alkoxy or optionally substituted phenyl,
- R* is a (C1 or C2)alkanediyl chain which is unsubstituted or substituted by one or two (C1-C4)alkyl radicals or by [(C1-C3)alkoxy]carbonyl,
- R7 is hydrogen or an unsubstituted or substituted aliphatic hydrocarbon radical,
- R8 is hydrogen, (C1-C6)alkyl, (C1-C6)alkoxy or optionally substituted phenyl,
- n′ is an integer from 1 to 5,
- W′ is a divalent heterocyclic radical from the group of partially unsaturated or heteroaromatic 5-membered heterocycles having 1 to 3 ring hetero atoms of the type of N and O, the ring containing at least one nitrogen atom and at most one oxygen atom.
21 more elements
Dependencies are inferred from the claim text.