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US 2006/0142426 A9Published application
Silica filled multi-viscoelastic response rubber
AssigneeThe Goodyear Tire & Rubber Company
InventorsGeorges Thielen, Howard Colvin
Life of this patent
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Abstract
The present invention relates to silica filled multi-viscoelastic response rubber which is thermomechanically mixed with an organosilicon compound during the non-productive mix stage and zinc oxide is added during the productive stage of mixing.
Claims20
A method for processing a rubber composition by a multi-stage mixing procedure comprising at least one non-productive stage and a productive stage:
- (A) wherein said non-productive stage is characterized by mixing a rubber composition at a rubber temperature in a range of from 140° C. to 190° C. for a mixing time of from 1 to 20 minutes, and said rubber composition comprises
- (1) 100 parts by weight of at least one sulfur vulcanizable elastomer wherein
- (a) from 40 to 100 parts by weight of said vulcanizable elastomer is a multi-viscoelastic response rubber;
- and
- (b) from zero to 60 parts by weight of said vulcanizable elastomer is a rubber containing olefinic unsaturation other than said multi-viscoelastic rubber;
- (2) from 0.1 to 25 phr of an organosilicon compound of the formula:
- Z-Alk-Sn-Alk-Z
- in which Z is selected from the group consisting of
- where R1 is an alkyl group of 1 to 4 carbon atoms, cyclohexyl or phenyl;
- R2 is alkoxy of 1 to 8 carbon atoms, or cycloalkoxy of 5 to 8 carbon atoms;
- Alk is a divalent hydrocarbon of 1 to 18 carbon atoms and n is from 2 to 8;
- (3) from 10 to 250 phr of a silica filler;
- and
- (4) the absence of zinc oxide to form a non-productive compound;
- (B) wherein said productive stage is characterized by mixing at a rubber temperature not to exceed 120° C., and the productive stage compound contains
- (1) said non-productive compound;
- (2) from 0.5 to 5 phr of a sulfur vulcanizing agent;
- and
- (3) from 1 to 8 phr of zinc oxide.
16 more elements
Dependencies are inferred from the claim text.