Sumanene and method for manufacturing the same
AssigneesNippon Shokubai Co., Ltd., Daicel Chemical Industries, Ltd., Kaneka Corporation
InventorsToshikazu Hirao, Hidehiro Sakurai, Taro Daiko
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AssigneesNippon Shokubai Co., Ltd., Daicel Chemical Industries, Ltd., Kaneka Corporation
InventorsToshikazu Hirao, Hidehiro Sakurai, Taro Daiko
Estimating the term…
The present invention provides Sumanene, its derivative and a method for manufacturing Sumanene and its derivative. As shown by a below-described scheme, benzotris(norbornadiene) (a below formula (87)) is firstly synthesized from norbornadiene (a below formula (86)). Then, the compound is subjected to a metathesis reaction so as to synthesize hexahydrosumanene (a below formula (88)), and it is dehydrogenized so as to obtain Sumanene (a below formula (84)). Thereby, Sumanene can be mass-synthesized under a moderate condition. In addition, a compound with a structure where a benzyl position of Sumanene is substituted by a N atom or an O atom can be obtained similarly, and various derivatives also can be obtained by further chemical modification of the compound. Sumanene and its derivative are suitable for electronic materials, synthesis raw materials for various kinds of fullerenes and heterofullerenes, and the like. Condition of the Reaction a) BuLi, t-BuOK, BrCH2CH2Br, THF, −78° C. to −45° C. subsequently CuI, a room temperature b) catalyst quantity of (PCy3)2RuCl2═CHPh, CH2═CH2, toluene, 0° C. to 80° C. c) DDQ, toluene, 110° C.
A compound represented by a below-described general formula (1), a tautomer of the compound, a stereoisomer of the compound, or a salt of any of the compound, the tautomer and the stereoisomer,
A compound represented by a below formula (76) or a salt of the compound,
A compound represented by a below formula (77′) or a salt of the compound,
Dependencies are inferred from the claim text.