(4,5,9,10-Tetrahydro-pyren-2-yl)-carbamic acid 4-(2-methylsulfanyl-alkyl)-3,5-dinitro-benzyl ester, method of synthesizing thereof, and molecular electronic device using the same

A molecular logic device comprising:

• a first electrode;
• a second electrode opposing side of the first electrode;
• and
• a logic gate arranged by molecular diode device as a unit device, wherein the molecular diode device includes a molecular film formed by combining between a compound having a following chemical formula and the second electrode.
• where R represents one of hydrogen H, methyl radical, alkyl radical, and acetyl radical that reacts with the surface of the second electrode, n represents an integer between 1 and 25.

A method of synthesizing a compound comprising:

• preparing 4,5,9,10-tetrahydro-pyren-2-yl-amine;
• preparing 4-acetylsulfanyl methyl-3-5-dinitro-benzyl chloroformate;
• and
• obtaining a compound having a following chemical formula by a coupling reaction between 4,5,9,10-tetrahydro-pyren-2-yl-amine and 4-acetylsulfanyl methyl-3,5-dinitro-benzyl chloroformate, so that the compound performs molecular rectifying action.
• where R represents one of hydrogen H, methyl radical, alkyl radical, and acetyl radical, and n represents an integer between 1 and 25.

A method of manufacturing a molecular electronic device comprising:

• preparing 4,5,9,10-tetrahydro-pyren-2-yl-amine;
• preparing 4-acetylsulfanyl methyl-3,5-dinitro-benzyl chloroformate;
• synthesizing a compound having a following chemical formula by a coupling reaction of the 4,5,9,10-tetrahydro-pyren-2-yl-amine with the 4-acetylsulfanyl methyl-3,5-dinitro-benzyl chloroformate, so that the compound performs molecular rectifying action;
• forming a molecular film by combining the compound with a surface of a first electrode;
• and
• forming a second electrode on the molecular film.
• where R represents one of hydrogen H, methyl radical, alkyl radical, and acetyl radical, and n represents an integer between 1 and 25.