Method and apparatus for metal removal by ION exchange

An apparatus for selectively removing metal ions of interest from a solution containing an oxidizing agent, solid particles and a first concentration of the metal ions, comprising:

• (a) an inlet adapted to receive the solution from a solution source;
• (b) a resin vessel in fluid communication with said inlet and adapted to receive the solution therefrom;
• (c) an ion-exchange resin disposed in said resin vessel, wherein said ion-exchange resin is resistant to damage by the oxidizing agent and is operative when in contact with the solution to exchange selected ones of the metal ions in the solution for selected preferred ions thereby to produce a treated solution having a second concentration of the metal ions that is lower than the first concentration;
• (d) a first outlet in fluid communication with the resin vessel and adapted to receive the treated solution therefrom;
• (e) a regenerant source in fluid communication with said resin vessel and operative to selectively provide thereto a regenerant solution that is operative when in contact with the ion-exchange resin to exchange ions in the regenerant solution for the metal ions of interest contained in the ion-exchange resin, thereby to form a regenerant waste solution containing a salt of the metal ions of interest;
• (f) a second outlet in fluid communication with said resin vessel and adapted to receive the regenerant waste solution therefrom;
• and
• (g) a valve system comprising a plurality of valves associated with a plurality of fluid pathways interconnecting selected ones of said inlet, said resin vessel, said regenerant source and said first and second outlets, whereby in a first state said valve system permits fluid flow through said inlet, through said resin vessel and through said first outlet thereby to define a first fluid pathway, and in a second state said valve system permits fluid flow from said regenerant source, through said resin vessel and through said second outlet thereby to define a second fluid pathway.

An apparatus for selectively removing metal ions of interest from a solution containing an oxidizing agent, solid particles and a first concentration of the metal ions, comprising:

• (a) an inlet adapted to receive the solution from a solution source;
• (b) a first resin vessel in fluid communication with said inlet and adapted to receive the solution therefrom;
• (c) a first ion-exchange resin disposed in said first resin vessel, wherein said first ion-exchange resin is resistant to damage by the oxidizing agent and is operative when in contact with the solution to exchange selected ones of the metal ions in the solution for selected preferred ions thereby to produce a treated solution having a second concentration of the metal ions that is lower than the first concentration;
• (d) a second resin vessel in fluid communication with said inlet and adapted to receive the solution therefrom;
• (e) a second ion-exchange resin disposed in said second resin vessel, wherein said second ion-exchange resin is resistant to damage by the oxidizing agent and is operative when in contact with the solution to exchange selected ones of the metal ions in the solution for selected preferred ions thereby to produce a treated solution having a second concentration of the metal ions that is lower than the first concentration;
• (f) a first outlet in fluid communication with said first resin vessel and said second resin vessel and adapted to selectively receive the treated solution therefrom;
• (g) a regenerant source in fluid communication with said first resin vessel and said second resin vessel and operative to selectively provide thereto a regenerant solution that is operative when in contact with the first and second ion-exchange resin respectively to exchange ions in the regenerant solution for the metal ions of interest contained in the first and second ion-exchange resin respectively, thereby to form a regenerant waste solution containing a salt of the metal ions of interest;
• (h) a second outlet in fluid communication with said first resin vessel and said second resin vessel and adapted to selectively receive the regenerant waste solution therefrom;
• and
• (i) a valve system comprising a plurality of valves associated with a plurality of fluid pathways interconnecting selected ones of said inlet, said first and second resin vessel, said regenerant source and said first and second outlets, whereby in a first state said valve system permits fluid flow through said inlet, through said first resin vessel and through said first outlet thereby to define a first fluid pathway, and permits fluid flow from said regenerant source, through said second resin vessel and through said second outlet thereby to define a second fluid pathway, and in a second state said valve system permits fluid flow through said inlet, through said second resin vessel and through said first outlet thereby to define a third fluid pathway, and permits fluid flow from said regenerant source, through said first resin vessel and through said second outlet thereby to define a fourth fluid pathway.