Method for removing filter cake from a horizontal wellbore using acid foam
AssigneeConocoPhillips Company
InventorAlbert Chan
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Abstract
A composition and method for removing a filter cake from a horizontal wellbore in a subterranean formation using a composition containing a inorganic or organic acidic material, a cationic fluorocarbon surfactant, an alkyl alcohol, water optionally containing ammonium chloride and at least one of an alkyl polyglycoside and a betaine surfactant to produce a stable foam used to remove filter cake from a horizontal wellbore.
Claims24
A method for removing a filter cake from a horizontal wellbore in a subterranean formation, the method comprising:
- a) forming a stable aqueous acidic foam, the foam being stable at 200° F. for at least about 3 to about 4 hours and comprising:
- i) an aqueous acidic material selected from the group consisting of from about 1 to about 20 weight percent of an inorganic acid, from about 1 to about 30 weight percent of an organic acid and mixtures thereof;
- ii) about 0.05 to about 3 weight percent of a cationic fluorocarbon surfactant;
- iii) about 0.1 to about 4 weight percent of an alkyl alcohol containing from about 4 to about 8 carbon atoms;
- iii) at least one of about 0.1 to about 4 weight percent of a betaine surfactant and about 0.25 to about 10 weight percent of an alkyl polyglycoside containing alkyl groups containing from about 8 to about 16 carbon atoms and mixtures thereof;
- and;
- iv) water optionally containing ammonium chloride;
- b) positioning the aqueous acidic foam in the horizontal wellbore;
- and,
- c) retaining the aqueous acidic foam in the horizontal wellbore for a time from about 2 to about 4 hours.
The method of claim 8 wherein the inorganic acid is hydrochloric acid.
The method of claim 1 wherein the cationic fluorocarbon co-surfactant fluorocarbon is selected from the group consisting of fluorinated alkyl quaternary ammonium chlorides. The method of claim 14 wherein the fluorinated alkyl group contains from 4 to 8 carbon atoms.
A composition for producing a stable acidic foam for use in removing filter cake from a horizontal wellbore in a subterranean formation, the foam being stable at 200° F. for at least about 3 to about 4 hours, the composition comprising:
- a) an acidic material selected from the group consisting of from about 1 to about 20 weight percent of an inorganic acid, from about 1 to about 30 weight percent of an organic acid and mixtures thereof;
- b) about 0.05 to about 3 weight percent of a cationic fluorocarbon co-surfactant;
- c) about 0.1 to about 4 weight percent of an alkyl alcohol containing from about 4 to about 8 carbon atoms;
- d) at least one of about 0.1 to about 4 weight percent of a betaine surfactant and about 0.25 to about 10 weight percent of an alkyl polyglycoside containing alkyl groups containing from about 8 to about 16 carbon atoms and mixtures thereof and;
- e) water optionally containing ammonium chloride.
Dependencies are inferred from the claim text.