Pesticidal 5-(acylamino) pyrazole derivatives

A compound of formula (I):

• wherein:
• R1 is (C1-C6)-haloalkyl, CN, NO2 or halogen;
• R2 is H, halogen or CH3;
• R3 is (C1-C3)-haloalkyl, (C1-C3)-haloalkoxy or S(O)p—(C1-C3)-haloalkyl;
• W is N or C—R4;
• R4 is halogen or CH3;
• A is (C2-C6)-alkylene or (C2-C6)-haloalkylene;
• or is (C3-C6)-alkylene in which a carbon in the chain is replaced by O, S, SO, SO2 or NR8 with the proviso that the replacing group is not bonded to the adjacent R5or carbonyl group;
• or is
• (C2-C6)-alkenylene or (C2-C6)-haloalkenylene;
• or
• is —[(C1-C3)-alkyl]r-aryl-[(C1-C3)-alkyl]s-, or —[(C1-C3)-alkyl]r-heterocyclyl-[(C1-C3)-alkyl]s-, or —[(C1-C3)-alkyl]r-(C3-C6)-cycloalkyl-[(C1-C3)-alkyl]s- or —[(C1-C3)-alkyl]r-(C5-C6)-cycloalkenyl-[(C1-C3)-alkyl]s-, in which last four mentioned groups the aryl, heterocyclyl, cycloalkyl and cycloalkenyl are unsubstituted or substituted by one or more radicals selected from the group consisting of halogen, (C1-C6)-alkyl, (C1-C6)-haloalkyl, (C1-C6)-alkoxy, (C1-C6)-haloalkoxy, OR11, CN, NO2, S(O)pR10, COR10, COOR10, CONR9R10, SO2NR9R10, NR9R10, OH, SO3H and (C1-C6)-alkylideneimino;
• R5 is CONR9R10 or CO2R10 when m is 0 or 1;
• or R5 is NR9R17 when m is 1;
• R6 is (C1-C3)-alkyl or (C1-C3)-haloalkyl;
• R7 is H, (C2-C6)-alkenyl, (C2-C6)-haloalkenyl, (C2-C6)-alkynyl, (C2-C6)-haloalkynyl, (C3-C7)-cycloalkyl, COR11, COR12, COR13, —CO2—(C1-C6)-alkyl, —CO2—(CH2)qR11, CO2—(CH2)qR13, —CO2—(C3-C7)-cycloalkyl, —CO2—(C1-C6)-alkyl-(C3-C7)-cycloalkyl, CO—(C2-C6)-alkenyl, —CH2R11 or CH2R13;
• or (C1-C6)-alkyl unsubstituted or substituted by one or more radicals selected from the group consisting of halogen, (C1-C6)-alkoxy, (C1-C6)-haloalkoxy, (C3-C7)-cycloalkyl, S(O)pR14, CO2—(C1-C6)-alkyl, —O(C═O)—(C1-C6)-alkyl, NR9R10, CONR9R10, SO2NR9R10, OH, CN, NO2, OR11, OR13,
• NR10COR9, NR11SO2R14 and COR12;
• R8 is R9, CO—R9, CO—R11, CO2R12 or CO—(C1-C6)-alkyl substituted by amino;
• R9 is H, (C1-C6)-alkyl, (C1-C6)-haloalkyl, (C2-C6)-alkenyl, (C2-C6)-haloalkenyl, (C2-C6)-alkynyl, (C2-C6)-haloalkynyl, (C3-C7)-cycloalkyl or —(C1-C6)-alkyl-(C3-C7)-cycloalkyl;
• R10 is R9, —[(C1-C6)-alkyl]q-R11, (C1-C3)-alkoxy-(C1-C3)-alkyl-, (C1-C3)-alkoxy-(C1-C3)-alkoxy-(C1-C3)-alkyl- or (C1-C3)-alkyl-S(O)p—(C1-C3)-alkyl-;
• or
• R9 and R10 or R9 and R17 each together with the respective attached N atom form a four- to seven-membered saturated ring which optionally contains an additional hetero atom in the ring which is selected from O, S and N, the ring being unsubstituted or substituted by one or more radicals selected from the group consisting of halogen, (C1-C6)-alkyl, (C1-C6)-haloalkyl and CO2—(C1-C6)-alkyl;
• R11 is phenyl unsubstituted or substituted by one or more radicals selected from the group consisting of halogen, (C1-C6)-alkyl, (C1-C6)-haloalkyl, (C1-C6)-alkoxy, (C1-C6)-haloalkoxy, OR16, CN, NO2, S(O)pR12, COR9, COOH, COOR12, CONR9R15, SO2NR9R15, NR9R15, OH, SO3H and (C1-C6)-alkylideneimino;
• R12 is (C1-C6)-alkyl or (C1-C6)-haloalkyl;
• R13 is heterocyclyl unsubstituted or substituted by one or more radicals selected from the group consisting of halogen, (C1-C4)-alkyl, (C1-C4)-haloalkyl, (C1-C4)-alkoxy, S(O)pR12, OH and oxo;
• R14 is (C1-C6)-alkyl, (C1-C6)-haloalkyl, (C3-C7)-cycloalkyl or —(C1-C6)-alkyl-(C3-C7)-cycloalkyl;
• R15 is H, (C1-C6)-alkyl, (C1-C6)-haloalkyl, (C3-C7)-cycloalkyl or —(C1-C6)-alkyl-(C3-C7)-cycloalkyl;
• R16 is phenyl unsubstituted or substituted by one or more radicals selected from the group consisting of halogen, (C1-C6)-alkyl, (C1-C6)-haloalkyl, (C1-C6)-alkoxy, (C1-C6)-haloalkoxy, CN, NO2, S(O)pR12, COR15, COOH, COOR12, CONR9R15, SO2NR9R15, NR9R15 and OH;
• R17 is R10, CO2(C1-C6)-alkyl, —CH2CO2(C1-C6)-alkyl, CO2CH2R18 or CO(C1-C6)-alkoxy;
• R18 is phenyl unsubstituted or substituted by one or more radicals selected from the group consisting of halogen, (C1-C6)-alkyl, (C1-C6)-haloalkyl and (C1-C6)-alkoxy;
• n and p are each independently 0, 1 or 2;
• m and q are each independently 0 or 1;
• r and s are each independently 0 or 1;
• and
• each heterocyclyl in the above-mentioned radicals is independently a heterocyclic radical having 3 to 7 ring atoms and 1, 2 or 3 hetero atoms in the ring selected from the group consisting of N, O and S;
• or a pesticidally acceptable salt thereof.