Dihydrocoumarin derivative, liquid crystal composition containing the same, and liquid crystal display device
AssigneesChisso Corporation, Chisso Petrochemical Corporation
InventorsAtsuko Fujita, Kouki Sago
Life of this patent
Estimating the term…
Abstract
A dihydrocoumarin ring-containing compound of the invention is represented by the following formula (1): wherein R represents hydrogen or an alkyl; A1 to A3 each represents 1,4-cyclohexylene or 1,4-phenylene; Z1 to Z3 each represents a single bond, —(CH2)2—, —CH2O—, —OCH2—, —CF2O—, —OCF2—, —CH═CH—, —CF═CF—, —C≡C—, —(CH2)4—, —O(CH2)2O—, —(CH2)2CF2O—, —(CH2)2OCF2—, —CF2O(CH2)2—, —OCF2(CH2)2—, —CH═CH—CH2O—, or —OCH2—CH═CH—; X represents hydrogen, fluorine, chlorine, —CN, —CF3, —CHF2, —CH2F, —OCF3, —OCHF2, or —OCH2F; G represents oxygen or sulfur; and n and m each represents 0, 1, or 2.
Claims36
A compound represented by the following formula (1):
- wherein
- R represents an alkyl having from 1 to 20 carbon atoms;
- and in this alkyl, any —CH2— may be replaced by —O—, —S—, —CO—, —CH═CH—, or —C≡C—;
- A1, A2, and A3 each independently represents 1,4-cyclohexylene or 1,4-phenylene;
- in the 1,4-cyclohexylene, any —CH2— may be replaced by —O—, —S—, or —CO—, and any —(CH2)2— may be replaced by —CH═CH—;
- in the 1,4-phenylene, any —CH═ may be replaced by —N═;
- and in these rings, any hydrogen may be replaced by fluorine, chlorine, —CN, —CF3, —CHF2, —CH2F, —OCF3, —OCHF2, or —OCH2F;
- Z1, Z2, and Z3 each independently represents a single bond, —(CH2)2—, —CH2O—, —OCH2—, —CF2O—, —OCF2—, —CH═CH—, —CF═CF—, —C≡C—, —(CH2)4—, —O(CH2)2O—, —(CH2)2CF2O—, —(CH2)2OCF2—, —CF2O(CH2)2—, —OCF2(CH2)2—, —CH═CH—CH2O—, or —OCH2—CH═CH—;
- X represents hydrogen, fluorine, chlorine, —CN, —CF3, —CHF2, —CH2F, —OCF3, —OCHF2—, or —OCH2F;
- G represents oxygen or sulfur;
- n and m each independently represents 0, 1, or 2;
- and
- in any one of the following (i) to (iii), R may represent hydrogen:
- (i) the total sum of n and m is 1 or 2;
- (ii) X represents fluorine, chlorine, —CN, —CF3, —CHF2, —CH2F, —OCF3, —OCHF2, or —OCH2F;
- and
- (iii) at least one of A1, A2, and A3 represents 1,4-phenylene in which any hydrogen is replaced by fluorine, chlorine, —CN, —CF3, —CHF2, —CH2F, —OCF3, —OCHF2, or —OCH2F.
A compound represented by the following formula (1):
- wherein
- R represents an alkyl having from 1 to 15 carbon atoms, an alkoxy having from 1 to 15 carbon atoms, an alkoxyalkyl having from 2 to 15 carbon atoms, or an alkenyl having from 2 to 15 carbon atoms;
- A1, A2, and A3 each independently represents 1,4-cyclohexylene, 1,4-phenylene, fluorinated 1,4-phenylene, or 1,3-dioxane-2,5-diyl;
- G represents oxygen or sulfur;
- Z1, Z2, and Z3 each independently represents a single bond, —(CH2)2—, —CH2O—, or —OCH2—,
- X represents fluorine or hydrogen;
- n and m each independently represents 0 or 1;
- and
- in any one of the following (iv) to (vi), R may represents hydrogen:
- (iv) the total sum of n and m is 1 or 2;
- (v) X represents fluorine;
- and
- (vi) at least one of A1, A2, and A3 represents 1,4-phenylene in which any hydrogen is replaced by fluorine.
A compound represented by any one of the following formulae (1a) to (1m):
- wherein R represents an alkyl having from 1 to 15 carbon atoms, an alkoxy having from 1 to 15 carbon atoms, or an alkenyl having from 2 to 15 carbon atoms;
- and Y1 to Y5 each independently represents hydrogen or fluorine.
A compound represented by any one of the following formulae:
- wherein R represents an alkyl having from 1 to 7 carbon atoms, an alkoxy having from 1 to 4 carbon atoms, or an alkenyl having from 2 to 7 carbon atoms.
Dependencies are inferred from the claim text.