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US 2006/0079709 A1Published application
Process for preparing cyclic ketones
AssigneeBayer MaterialScience AG
InventorsChristoph Gurtler, Jorg Kirchhoff, Ido Schwarz
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Abstract
The present invention provides a process for preparing cyclic 1,3-keto esters in the absence of solvent, using solid-state or high viscosity reactors.
Claims7
Process for preparing cyclic ketones of the general formula (I),
- where
- X is an electron-pulling group,
- R1 and R2 are each, independently of one another, H, C1-C20-(cyclo)alkyl, C6-C24-aryl, C1-C20-(cyclo)alkyl ester or C1-C20-(cyclo)alkylamide, C6-C24-aryl ester or C6-C24-arylamide, a mixed aliphatic/aromatic radical having from 1 to 24 carbon atoms, which can also be part of a 4- to 6-membered ring,
- wherein a metal base is reacted with a compound of the general formula (II)
- where, independently of one another, the radicals
- R1 and R2 are as defined above,
- R3 is an alkyl or aryl radical and
- X is an electron-pulling group,
- in a solid-state reactor or high-viscosity reactor without additional solvents being used.
6 more elements
Dependencies are inferred from the claim text.