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US 2006/0069282 A1Published application
Process for producing aromatic nitrile compound
AssigneeIhara Chemical Industry Co., Ltd.
InventorKentaro Kawazoe
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Abstract
A novel process for industrially producing an aromatic nitrile compound represented by the following general formula (3): characterized in that one of an aromatic hydroxymethyl compound, an aromatic alkoxymethyl compound and an aromatic aldehyde compound, all represented by the following general formula (1): or a mixture thereof is reacted with an oxidized bromine compound represented by the general formula (2) MBrOm (2) in the presence of an acid catalyst and either ammonia or an ammonium sat.
Claims8
A process for producing an aromatic nitrile compound represented by the following general formula (3):
- [wherein ring A is an aromatic hetero-cycle having at least one hetero-atom or a phenyl ring;
- n is an integer of 1 to 9;
- R is a hydrogen atom, an alkyl group, a hydroxyl group, an alkoxy group, a hydroxyalkyl group, an alkoxyalkyl group, a haloalkyl group, a carboxyl group or a metal salt thereof, an alkoxycarbonyl group, a halogen atom, a nitro group, an amino group, an alkylamino group, a dialkylamino group, an alkylcarbonylamino group, a cyano group, a formyl group, an alkylcarbonyl group, or a substituted or unsubstituted phenyl group;
- q is an integer of 1 to 9 with a proviso that (q-n) is zero or a positive integer;
- when (q-n) is 2 or more, a plurality of Rs may be the same or different;
- two Rs may be bonded to each other to form a ring], characterized in that one of an aromatic hydroxymethyl compound, an aromatic alkoxymethyl compound and an aromatic aldehyde compound, all represented by the following general formula (1):
- (wherein X is a hydroxymethyl group, an alkoxymethyl group or a formyl group;
- n, R and q have the same definitions as given above), or a mixture thereof is reacted with an oxidized bromine compound represented by the general formula (2)
- MBrOm (2)
- (wherein M is a hydrogen atom or a metal atom, and m is an integer of 1 to 3) in the presence of an acid catalyst and either ammonia or an ammonium salt.
7 more elements
Dependencies are inferred from the claim text.