Polyimide having an alcoholic hydroxyl group and a process for the preparation thereof
AssigneeShin-Etsu Chemical Co., Ltd.
InventorsMichihiro Sugo, Hideto Kato, Tomoyuki Goto
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AssigneeShin-Etsu Chemical Co., Ltd.
InventorsMichihiro Sugo, Hideto Kato, Tomoyuki Goto
Estimating the term…
This invention relates to a novel polyimide silicone having an alcoholic hydroxyl group and a process for the preparation thereof. The polyimide of the invention having a primary alcoholic hydroxyl group is represented by the following general formula (1), wherein X represents a tetravalent organic group, Y represents a divalent group having at least one monovalent group selected from the group consisting of a phenolic hydroxyl group and a carboxyl group, with at least one being a divalent organic group having an alcoholic hydroxyl group, Z represents a divalent organic group, W represents a divalent organic group having an organosiloxane structure, k is a positive number, and each of m and n is equal to 0 (zero) or a positive number, with 0.1≦k/(k+m+n)≦1, 0≦m/(k+m+n)≦0.8, 0≦n/(k+m+n)≦0.8.
Polyimide having a primary alcoholic hydroxyl group and represented by the following general formula (1),
A process for the preparation of a polyimide having an alcoholic hydroxyl group represented by the general formula (1), wherein an acid dianhydride is reacted with a diamine having at least one selected from a phenolic hydroxyl group and a carboxyl group, optionally a diamine having neither a phenolic hydroxyl group nor a carboxyl group, and also optionally a dimainosilicone, to obtain a polyamic acid, subsequently the resulting polyamic acid is subjected to dehydration cyclization to obtain a polyimide having at least one selected from a phenolic hydroxyl group and a carboxyl group and represented by the general formula (5),
Dependencies are inferred from the claim text.