Process for making cosmetic compositions using polyether siloxane copolymer network compositions

A method for making a cosmetic composition comprising preparing a cosmetic composition comprising an aqueous emulsion where the continuous phase comprises water and the discontinuous phase comprises a composition comprising the reaction product of:

• MaMHbMEcDdDHeDEfTgTHhTEiQj
• where
• M=R1R2R3SiO1/2;
• MH=R4R5H SiO1/2;
• ME=R6R7RESiO1/2;
• D=R8R9SiO2/2;
• DH=R10HSiO2/2;
• DE=R11RESiO2/2;
• T=R12SiO3/2;
• T H=HSiO3/2;
• TE=RESiO3/2;
• and
• Q=SiO4/2;
• where R1, R2, R3, R8, R9 and R12 are independently monovalent hydrocarbon radicals having from one to sixty carbon atoms;
• R4, R5 and R10 are independently monovalent hydrocarbon radicals having from one to sixty carbon atoms or hydrogen;
• R6, R7, R11 are independently monovalent hydrocarbon radicals having from one to sixty carbon atoms or RE;
• each RE is independently a monovalent hydrocarbon radical containing one or more oxirane moieties having from one to sixty carbon atoms;
• the stoichiometric subscripts a, b, c, d, e, f, g, h, i, and j are either zero or positive subject to the following limitations:
• a+b+c>1;
• b+e+h>1;
• c+f+i>1;
• b+e+h>c+f+i;
• wherein said composition having an original volume may be swollen by a low molecular weight silicone fluid from 2 to 1,000 times its original volume wherein said cosmetic composition exhibits high stability and resistance to syneresis.

A method for making a cosmetic composition comprising preparing a cosmetic composition comprising an aqueous emulsion where the discontinuous phase comprises water and the continuous phase comprises a composition comprising the reaction product of:

• MaMHbMEcDdDHeDEfTgTHhTEiQj
• where
• M=R1R2R3SiO1/2;
• MH=R4R5H SiO1/2;
• ME=R6R7RESiO1/2;
• D=R8R9SiO2/2;
• DH=R10HSiO2/2;
• DE=R11RESiO2/2;
• T=R12SiO3/2;
• T H=HSiO3/2;
• TE=RESiO3/2;
• and
• Q=SiO4/2;
• where R1, R2, R3, R8, R9 and R12 are independently monovalent hydrocarbon radicals having from one to sixty carbon atoms;
• R4, R5 and R10 are independently monovalent hydrocarbon radicals having from one to sixty carbon atoms or hydrogen;
• R6, R7, R11 are independently monovalent hydrocarbon radicals having from one to sixty carbon atoms or RE;
• each RE is independently a monovalent hydrocarbon radical containing one or more oxirane moieties having from one to sixty carbon atoms;
• the stoichiometric subscripts a, b, c, d, e, f, g, h, i, and j are either zero or positive subject to the following limitations:
• a+b+c>1;
• b+e+h>1;
• c+f+i>1;
• b+e+h>c+f+i;
• wherein said composition having an original volume may be swollen by a low molecular weight silicone fluid from 2 to 1,000 times its original volume wherein said cosmetic composition exhibits high stability and resistance to syneresis.

A method for making a cosmetic composition comprising preparing a cosmetic composition comprising a non-aqueous emulsion where the discontinuous phase comprises a non-aqueous hydroxylic solvent and the continuous phase comprises a composition comprising the reaction product of:

• MaMHbMEcDdDHeDEfTgTHhTEiQj
• where
• M=R1R2R3SiO1/2;
• MH=R4R5H SiO1/2;
• ME=R6R7RESiO1/2;
• D=R8R9SiO2/2;
• DH=R10HSiO2/2;
• DE=R11RESiO2/2;
• T=R12SiO3/2;
• T H=HSiO3/2;
• TE=RESiO3/2;
• and
• Q=SiO4/2;
• where R1, R2, R3, R8, R9 and R12 are independently monovalent hydrocarbon radicals having from one to sixty carbon atoms;
• R4, R5 and R10 are independently monovalent hydrocarbon radicals having from one to sixty carbon atoms or hydrogen;
• R6, R7, R11 are independently monovalent hydrocarbon radicals having from one to sixty carbon atoms or RE;
• each RE is independently a monovalent hydrocarbon radical containing one or more oxirane moieties having from one to sixty carbon atoms;
• the stoichiometric subscripts a, b, c, d, e, f, g, h, i, and j are either zero or positive subject to the following limitations:
• a+b+c>1;
• b+e+h>1;
• c+f+i>1;
• b+e+h>c+f+i;
• wherein said composition having an original volume may be swollen by a low molecular weight silicone fluid from 2 to 1,000 times its original volume wherein said cosmetic composition exhibits high stability and resistance to syneresis.

A method for making a cosmetic composition comprising preparing a cosmetic composition comprising a non-aqueous emulsion where the continuous phase comprises a non-aqueous hydroxylic solvent and the discontinuous phase comprises a composition comprising the reaction product of:

• MaMHbMEcDdDHeDEfTgTHhTEiQj
• where
• M=R1R2R3SiO1/2;
• MH=R4R5H SiO1/2;
• ME=R6R7RESiO1/2;
• D=R8R9SiO2/2;
• DH=R10HSiO2/2;
• DE=R11RESiO2/2;
• T=R12SiO3/2;
• T H=HSiO3/2;
• TE=RESiO3/2;
• and
• Q=SiO4/2;
• where R1, R2, R3, R8, R9 and R12 are independently monovalent hydrocarbon radicals having from one to sixty carbon atoms;
• R4, R5 and R10 are independently monovalent hydrocarbon radicals having from one to sixty carbon atoms or hydrogen;
• R6, R7, R11 are independently monovalent hydrocarbon radicals having from one to sixty carbon atoms or RE;
• each RE is independently a monovalent hydrocarbon radical containing one or more oxirane moieties having from one to sixty carbon atoms;
• the stoichiometric subscripts a, b, c, d, e, f, g, h, i, and j are either zero or positive subject to the following limitations:
• a+b+c>1;
• b+e+h>1;
• c+f+i>1;
• b+e+h>c+f+i;
• wherein said composition having an original volume may be swollen by a low molecular weight silicone fluid from 2 to 1,000 times its original volume wherein said cosmetic composition exhibits high stability and resistance to syneresis.