Synergistic uv absorber combination
AssigneeCiba Specialty Chemicals Corporation
InventorsAdalbert Braig, David Leppard, Frederique Wendeborn
Life of this patent
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Abstract
A stabilizer composition comprising (A) a compound of the formula (I) wherein R is (CH2—CH2—O—)n, —R2; —CH2—CH(OH)—CH2—O—R2; or —CH(R3)—CO—O—R4; n is 0 or 1; R2 is C1-C13alkyl or C2C20alkenyl or C6-C12aryl or CO—C1-C18alkyl; R3 is H or C1-C8 alkyl; R4 is C1-C12alkyl or C2-C12alkenyl or C5C6cycloalkyl; and (B) one or more compounds selected from benzotriazoles of the formula (IIa), 2-hydroxybenzophenones of the formula (IIb), oxalanilides of the formula (IIc), 2-hydroxyphenyltriazines of formula (IId), cinnamates of formula (IIe), and benzoates of formula (IIf) as defined in claim 1, is especially effective towards stabilizing organic materials against degradation induced by light, heat or oxidation.
Claims17
A composition comprising
- (A) a compound of the formula I
- wherein R is (CH2—CH2—O—)n—R2;
- —CH2—CH(OH)—CH2—O—R2;
- or —CH(R3)—CO—O—R4;
- n is 0 or 1;
- R2 is C1-C13alkyl or C2-C20alkenyl or C6-C12aryl or CO—C1-C18alkyl;
- R3 is H or C1-C8alkyl;
- R4 is C1-C12alkyl or C2-C12alkenyl or C5-C6cycloalkyl;
- and
- (B) a compound selected from benzotriazoles of the formula (IIa), 2-hydroxybenzophenones of the formula (IIb), oxalanilides of the formula (IIc), 2-hydroxyphenyltriazines of formula (IId), cinnamates of formula (IIe), and benzoates of formula (IIf)
- wherein T1 is hydrogen, C1-C18alkyl, or C1-C18alkyl which is substituted by phenyl,
- or T1 is a group of the formula
- L1 is a divalent group, for example —(CH2)n—, where n is from the range 1-8;
- T2 is hydrogen, C1-C18alkyl, or is C1-C18alkyl which is substituted by COOT5, C1-C18alkoxy, hydroxyl, phenyl or C2-C18acyloxy;
- T3 is hydrogen, halogen, C1-C18alkyl, C1-C18alkoxy, C2-C18acyloxy, phenyl, or is perfluoroalkyl of 1 to 12 carbon atoms;
- T5 is C1-C18alkyl or C4-C50alkyl interrupted by one or more O and/or substituted by OH or by a group
- G1, G2 and G3 independently are hydrogen, hydroxy or C1-C18alkoxy;
- wherein
- G4, G5, G6 and G7 independently are hydrogen, C1-C12alkyl or C1-C12alkoxy;
- wherein
- G8 is C1-C18alkyl, or is C4-C18alkyl which is interrupted by COO or OCO or O, or is interrupted by O and substituted by OH;
- G9, G10, G11 and G12 independently are hydrogen, methyl, hydroxy or OG8;
- wherein
- m is an integer from 1 to 4;
- G15 is hydrogen or phenyl;
- if n is 1, G16 is COO-G19;
- if n is 2, G16 is C2-C12alkane-dioxycarbonyl;
- if n is 3, G16 is C3-C12alkane-trioxycarbonyl;
- if n is 4, G16 is C4-C12alkane-tetraoxycarbonyl;
- G17 is hydrogen, CN, or is COO-G19;
- G18 is hydrogen or methoxy;
- G19 is C1-C18alkyl;
- wherein
- k is 1 or 2;
- when k is 1, G20 is C1-C18alkyl, phenyl or phenyl substituted by C1-C12alkyl, and G21 is hydrogen;
- when k is 2, G20 and G21 together are the tetravalent group
- G22 and G24 independently are hydrogen or C1-C8alkyl;
- G23 is hydrogen or hydroxy,
- provided that R in formula (I) is (CH2—CH2—O—)n—R2 if component (B) contains a 2-hydroxyphenyltriazine of formula (IId) wherein G9, G10, G11 or G12 are methyl.
Dependencies are inferred from the claim text.