Gloss pigments having high colour saturation
AssigneeCiba Specialty Chemicals Corporation
InventorPatrice Bujard
Life of this patent
Estimating the term…
Abstract
The invention relates to coloured gloss pigments having specific particle dimensions comprising a transparent core of a silicon oxide of the composition SiO0.03 to SiO0.95 and, optionally, further coatings of silicon dioxide, carbon, a partially transparent metal and/or a dielectric of high refractive index, to a coating method suitable therefor wherein metallic silicon is vapour-deposited in the presence of a low oxygen partial pressure, to the use of such gloss pigments in pigmenting plastics, surface coatings, printing inks and cosmetic compositions, and also to pigmented compositions comprising such gloss pigments.
Claims10
A pigment the particles of which have a length of from 2 μm to 5 mm, a width of from 2 μm to 2 mm and a thickness of from 50 nm to 1.5 μm and a ratio of length to thickness of at least 2:1, the particles having a core SD having two substantially parallel faces, the distance between which is the shortest axis of the core, and optionally having layers QZ and/or DM applied to those parallel faces or to the entire surface, and wherein
- the core SD has a thickness of from 20 to 350 nm and comprises from 50 to 97 atom % silicon, bonded to from 3 to 95 atom % oxygen per 100 atom % silicon;
- optionally, a layer QZ having a thickness of from 0 to 500 nm is present, which is applied to the core SD and comprises from 17 to 51 atom % silicon, which is bonded to more than 95 atom % oxygen per 100 atom % silicon;
- and
- optionally, a layer DM having a thickness of from 0 to 300 nm is present, which has a transparency of from 50 to 100% and a complex refractive index Ñ=n+ik according to the condition {square root}{square root over (n2+k2)}≧1.5 at the wavelength of maximum visible reflection of the particles, which is substantially composed of carbon, an organic compound, a metal, a dielectric or a mixture thereof, and which is either on the core SD or, in the presence of a layer QZ, is separated from the core SD by the layer QZ.
A surface coating wherein measurement of the reflection under D65 illumination results in a hue angle h of from 350 to 30 at a measurement angle of 80° to the surface and in a hue angle h of from 70 to 120 at a measurement angle of 30° to the surface.
Dependencies are inferred from the claim text.