Catalysts
AssigneeJohnson Matthey PLC
InventorsNeil Caplan, Frederick Hancock
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Abstract
A process for performing a catalytic Diels-Alder reaction by reacting a diene with a dienophile in the presence of a heterogeneous catalyst comprising a zeolitic material exchanged or impregnated with ions of a Lewis acidic metal is described. The catalyst, for example, copper-exchanged zeolite Y, may be treated with chiral bis(imine) compounds to direct the chirality of the reaction products. The catalyst can be separated from the reaction mixture and re-used in further Diels Alder reactions.
Claims14
A process for performing an enantioselective catalytic Diels-Alder reaction by reacting a diene with a dienophile in the presence of a heterogeneous catalyst comprising a zeolitic material exchanged or impregnated with ions of copper, and a chiral bis(oxazoline).
Dependencies are inferred from the claim text.