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US 2005/0033076 A1Published application
Preparation of preparing substituted indanones
AssigneeBasell Polyolefine GmbH
InventorsCarsten Bingel, Markus Goeres, Volker Fraaije, Andreas Winter
Life of this patent
Estimating the term…
Abstract
A process for the preparation of indanones of the formula II from indanones of the formula I or of indanones of the formula IIa from indanones of the formula Ia comprises reacting an indanone of the formula I or Ia with a coupling component.
Claims8
-13. (canceled)
A metallocene compound of the formula VI
- where
- R1 is a linear, branched or cyclic C1-C8-alkyl group which may bear one or more identical or different fluorine or chlorine substituents, a phenyl group which may bear one or more identical or different fluorine or chlorine substituents, a C1-C12-alkylaryl or arylalkyl group, where the alkyl part may bear one or more identical or different fluorine or chlorine subsituents and the aryl part may bear one or more identical or different fluorine or chlorine subsituents, a C2-C8-alkenyl group or a C2-C8-alkynyl group, a C8-C12-arylalkyl group which may bear one or more identical or different fluorine or chlorine subsituents, or R1 is an OR2, SiR23 or —OSiR23 group, where R2 are identical or different and are each a C1-C4-alkyl group or phenyl group or R1 is a C, —C1-6-heterocyclic group, where the heteroatoms are oxygen, nitrogen, sulfur or silicon and the group may in turn bear C1-C10-radicals or heteroatoms as substituents.
- M is titanium, zirconium or hafnium,
- R9 and R10 are identical or different and are hydrogen, hydroxy, C1-C10-alkyl, C1-C10-alkoxy, C1-C10-alkyl, C1-C10-aryloxy, C2-C10-alkenyl, C7-C40-arylalkyl, C7-C40-alkyaryl or C8-C40-arylalkenyl,
- x is zero or 1,
- R3 is 4-(C4-C8-alkyl) phenyl, where the (C4-C8-alkyl) group is a branched C4-C8-alkyl group,
- Y4 and Y6 are hydrogen Y5 is hydrogen or R3,
- R11 is a bridging group of the formula
- where M2 is carbon, silicon, germanium or tin,
- p is 1, 2 or 3,
- R12 and R13 are identical or different and are hydrogen, halogen C1-C20-alkyl, C6-C14— aryl, C1-C10— alkoxy, C2-C10— alkenyl, C7-C20-arylalky, C7-C20-alkyaryl, C6-C10— aryloxy, C1-C10-fluoralkyl, C6-C10-haloaryl or C2-C10-alkynyl or R12 and R13 together with the atom connecting them from a ring, wherein the radicals having the same designation on the two indenyl ligands can be identical or different from one another.
8 more elements
Dependencies are inferred from the claim text.