Heterogeneously catalyzed partial direct oxidation of propane and/or isobutane
AssigneeBASF SE
InventorsOtto Machhammer, Sven Crone, Frieder Borgmeier, Klaus Joachim Muller-Engel, Christoph Adami, Armin Diefenbacher
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Abstract
A process for heterogeneously catalyzed partial direct oxidation of propane and/or isobutane, in which target product is removed in a workup stage from the product gas mixture obtained in the reaction stage, the remaining residual product gas mixture is divided into two portions of the same composition, one portion is recycled into the reaction stage and the other portion is discharged, and both the reaction stage and the workup stage are operated at elevated pressure.
Claims32
A process for heterogeneously catalyzed partial direct oxidation of propane and/or isobutane to at least one of the target products acrylic acid, methacrylic acid, by feeding a starting reaction gas mixture comprising propane and/or isobutane, molecular oxygen and at least one inert diluent gas and having a inlet pressure P1 to a reaction stage which, apart from an inlet for the starting reaction gas mixture, optionally further inlets for auxiliary gases, and an outlet for the product gas mixture, is sealed on the gas side, in the reaction stage directly oxidizing the propane and/or isobutane present in the starting reaction gas mixture partially to at least one target product by passing the starting reaction gas mixture at elevated temperature over a solid state catalyst, and conducting the reaction gas mixture as a product gas mixture comprising at least one target product and having the outlet pressure P2 out of the reaction stage and, with this pressure P2, into a workup stage which, apart from an inlet for the product gas mixture, optionally further inlets for auxiliary gases, and an outlet for the residual product gas mixture, is sealed on the gas side, in the workup stage basically separating target product present in the product gas mixture of the reaction stage from said product gas mixture into a liquid phase and conducting the remaining residual product gas mixture which comprises not only propane and/or isobutane and also in some cases propene and/or isobutene and has the outlet pressure P3, where P3<P1, out of the workup stage and recycling propane and/or isobutane present in the residual product gas mixture into the reaction stage, which comprises selecting P1 in such a way that P3≧1.5 bar and dividing the residual product gas mixture into two portions of the same composition and discharging one portion as output and recycling the other portion as cycle gas and feeding it back to the reaction stage, compressed to the inlet pressure P1, as a constituent of the starting reaction gas mixture.
Dependencies are inferred from the claim text.