Polyester compositions of low residual aldehyde content
AssigneeCiba Specialty Chemicals Corporation
InventorsPaul Angelo Odorisio, Stephan Mark Andrews
Life of this patent
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Abstract
A mixture of a polyester, such as poly(ethylene terephthalate) PET, and a suitable stabilizer selected from the group consisting of polyhydric alcohol-containing polymers and copolymers derived from 2-propenoic acid ester monomers, when extrusion compounded exhibits a lower residual acetaldehyde content than does PET alone when similarly treated. The invention pertains to any polyester used in the manufacture of bottles or containers which in turn are used to store consumer materials, especially food, beverages and most especially water.
Claims12
A polyester composition, stabilized against the formation of aldehydic contaminants during melt processing of said composition, which comprises
- (a) a polyester, and
- (b) an effective stabilizing amount of at least one polymer or copolymer derived from at least one 2-propenoic acid ester monomer of the formula I
- 6
- where R1, R2 and R3 are independently hydrogen, straight or branched chain alkyl of 1 to 24 carbon atoms, cycloalkyl of 5 to 12 carbon atoms, aralkyl of 7 to 15 carbon atoms, or said alkyl, cycloalkyl or aralkyl which is further substituted by one or more —OR5, —NR6R7, —CO2R8 or —CON R9R10 wherein R5, R6, R7, R8, R9, and R10 are independently hydrogen or straight or branched chain alkyl of 1 to 18 carbon atoms;
- or
- R1, R2, R3 are independently a group —CO2R4,
- R4 is a polyhydric alcohol substituent of the formula -E-(OH)n where
- n is 2 to 4000, and
- E is a hydrocarbylene moiety.
A mono- or multi-layered plastic container or film, stabilized against the formation of aldehydic contaminants during melt processing of said container or film, comprising at least one layer which comprises
- (a) a polyester, and
- (b) an effective stabilizing amount of at least one polymer or copolymer derived from at least one 2-propenoic acid ester monomer of the formula I
- 7
- where R1, R2 and R3 are independently hydrogen, straight or branched chain alkyl of 1 to 24 carbon atoms, cycloalkyl of 5 to 12 carbon atoms, aralkyl of 7 to 15 carbon atoms, or said alkyl, cycloalkyl or aralkyl which is further substituted by one or more —OR5, —NR6R7, —CO2R8 or —CONR9R10 wherein R5, R6, R7, R8, R9, and R10 are independently hydrogen or straight or branched chain alkyl of 1 to 18 carbon atoms;
- or
- R1, R2, R3 are independently a group —CO2R4,
- R4 is a polyhydric alcohol substituent of the formula -E-(OH)n where
- n is 2 to 4000, and
- E is a hydrocarbylene moiety.
A process for preventing the formation of aldehydic contaminants during melt processing of a polyester which comprises incorporating into said polyester an effective stabilizing amount of at least one polymer or copolymer derived from at least one 2-propenoic acid ester monomer of the formula I
- 8
- where R1, R2 and R3 are independently hydrogen, straight or branched chain alkyl of 1 to 24 carbon atoms, cycloalkyl of 5 to 12 carbon atoms, aralkyl of 7 to 15 carbon atoms, or said alkyl, cycloalkyl or aralkyl which is further substituted by one or more —OR5, —NR6R7, —CO2R8 or —CONR9R10 wherein R5, R6, R7, R8, R9, and R10 are independently hydrogen or straight or branched chain alkyl of 1 to 18 carbon atoms;
- or R1, R2, R3 are independently a group —CO2R4,
- R4 is a polyhydric alcohol substituent of the formula -E-(OH)n where
- n is 2 to 4000, and.
- E is a hydrocarbylene moiety.
A polyester composition, stabilized against the formation of aldehydic contaminants during melt processing of said composition, which comprises
- (a) a polyester, and
- (b) an effective stabilizing amount of at least one polymer or copolymer derived from at least one 2-propenoic acid ester monomer of the formula I
- 9
- where R1, R2 and R3 are independently hydrogen, straight or branched chain alkyl of 1 to 24 carbon atoms, cycloalkyl of 5 to 12 carbon atoms, aralkyl of 7 to 15 carbon atoms, or said alkyl, cycloalkyl or aralkyl which is further substituted by one or more —OR5, —NR6R7, —CO2R8 or —CONRgR10 wherein R5, R6, R7, R8, R9, and R10 are independently hydrogen or straight or branched chain alkyl of 1 to 18 carbon atoms;
- or
- R1, R2, R3 are independently a group —CO2R4,
- R4 is a polyhydric alcohol substituent of the formula -E-(OH)n where
- n is 2 to 4000, and
- E is a hydrocarbylene moiety;
- and optionally
- (c) an effective stabilizing amount of a polymer which is poly(vinyl alcohol) or an ethylene/vinyl alcohol copolymer;
- and optionally
- (d) an effective stabilizing amount of a polyhydric alcohol;
- and optionally
- (e) an effective stabilizing amount of a polymer which is polyacrylamide, polymethacrylamide or an acrylamide or methacrylamide copolymer with at least one ethylenically unsubstituted comonomer, wherein the polyhydric alcohol is of the formula G-(OH)n where n is 2 to 4000, and G is a hydrocarbyl moiety;
- and optionally
- (f) an effective stabilizing amount of at least one compound selected from the group consisting of
- i.) hydroxylamine stabilizers,
- ii.) substituted hydroxylamine stabilizers,
- iii.) nitrone stabilizers, and
- iv.) amine oxide stabilizers.
A co-polymer of glycerol mono-methacrylate and styrene.
Dependencies are inferred from the claim text.