Preparation of flame retarded polyisocyanurate foams
OwnerElbert F. Feske, William R. Brown +2inventors
InventorsElbert F. Feske, William R. Brown, Susan D. Landry, Arthur G. Mack
Life of this patent
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OwnerElbert F. Feske, William R. Brown +2inventors
InventorsElbert F. Feske, William R. Brown, Susan D. Landry, Arthur G. Mack
Estimating the term…
Polyisocyanurate foams are produced by mixing at least one organic isocyanate and at least one polyol in the presence of at least one aliphatic or cycloaliphatic C4-C7 hydrocarbon having a boiling point of 70° C. or less at 760 millimeters pressure, at least one trimerization catalyst, at least one alkylene glycol ester of tetrabromophthalic anhydride, and at least one phosphorus ester selected from (i) tri(chloroalkyl)phosphate in which each alkyl group has 2 or 3 carbon atoms, (ii) dialkyl alkanephosphonates in which each alkyl group has 1 or 2 carbon atoms and in which the alkane group has 1 or 2 carbon atoms, and (iii) triethylphosphate, and wherein the organic isocyanate and polyol components are proportioned to form a polyisocyanurate having an isocyanate index in the range of about 240 to about 280.
A method of preparing a polyisocyanurate foam, which method comprises mixing at least one organic isocyanate and at least one polyol in the presence of at least one aliphatic or cycloaliphatic C4-C7 hydrocarbon having a boiling point of 70° C. or less at 760 millimeters pressure, at least one trimerization catalyst, at least one alkylene glycol ester of tetrabromophthalic anhydride, and at least one phosphorus ester selected from (i) tri(chloroalkyl)phosphate in which each alkyl group has 2 or 3 carbon atoms, (ii) dialkyl alkanephosphonates in which each alkyl group has 1 or 2 carbon atoms and in which the alkane group has 1 or 2 carbon atoms, and (iii) triethylphosphate, and wherein the organic isocyanate and polyol components are proportioned to form a polyisocyanurate having an isocyanate index in the range of about 240 to about 280.
A polyisocyanurate foam having an isocyanate index in the range of about 240 to about 280 formed from at least one isocyanate and at least one polyol in the presence of at least one aliphatic or cycloaliphatic C4-C7 hydrocarbon having a boiling point of 70° C. or less at 760 millimeters pressure, at least one trimerization catalyst, at least one alkylene glycol ester of tetrabromophthalic anhydride, and at least one phosphorus ester selected from (i) tri(chloroalkyl)phosphate in which each alkyl group has 2 or 3 carbon atoms, (ii) dialkyl alkanephosphonates in which each alkyl group has 1 or 2 carbon atoms and in which the alkane group has 1 or 2 carbon atoms, and (iii) triethylphosphate.
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