Process for stabilizing unsaturated organosilicon compounds
AssigneeWacker Chemie AG
InventorJuergen Pfeiffer
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Abstract
A process for stabilizing organosilicon compounds bearing unsaturated groups during their preparation, distillation, and/or storage, the organosilicon compounds bearing unsaturated groups having been obtained by reacting a haloalkylsilane with a salt of an unsaturated organic acid, by adding one or more compounds of the formula I 1 wherein R1 and R2 are identical or different linear or branched C1-20 alkyl, and the radicals R3 are identical or different and are hydrogen or linear or branched alkyl radicals having 1-20 carbon atoms.
Claims8
A process for stabilizing organosilicon compounds bearing unsaturated groups of the formula II:
- H2C═C(R4)[C(O)O]w(O)x—(R5)y—Si(R6)z(OR7)3-z II
- during one or more of their preparation, distillation, or storage;
- wherein R4 is a hydrogen atom or a linear or branched hydrocarbon radical having 1-10 carbon atoms;
- R5 is a linear, cyclic or branched hydrocarbon radical having 1-40 carbon atoms optionally containing one or more heteroatoms selected from the group consisting of nitrogen, oxygen, sulfur and phosphorus;
- R6 and R7 are independently linear, cyclic, or branched hydrocarbon radicals having 1-10 carbon atoms, wherein w is 0 or 1, x is 0 or 1, y is 0 or 1, and z is 0, 1 or 2, and wherein w and x are not both 1 simultaneously, the compounds of the formula II having been obtained by reacting a haloalkylsilane with a salt of an unsaturated organic acid, by adding an effective stabilizing amount of one or more compounds of the formula I:
- 4
- wherein R1 and R2 are identical or different linear or branched alkyl radicals having 1-20 carbon atoms and the radicals R3 are identical or different substituents selected from the groups consisting of hydrogen and linear and branched alkyl radicals having 1-20 carbon atoms.
Dependencies are inferred from the claim text.