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US 2004/0171857 A1Published application
Catalyst for the production of olefin polymers
OwnerChunming Wanginventor
Life of this patent
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Abstract
A catalyst composition for the polymerization of olefins is provided, comprising a cyclopentadienyl transition metal catalyst and an activating co-catalyst.
Claims2
A compound having the formula:
- 5
- wherein:
- R1, R2, R3 and R4 are each independently selected from among hydrogen and C1-C8 hydrocarbyl groups, wherein none, one or two pairs of substituents selected from the group consisting of R1, R2, R3 and R4 are linked to form saturated or unsaturated rings;
- M is an atom selected from among the elements of Groups IV, V and VI;
- m is 1, 2, 3 or 4;
- the or each X is selected from among halide elements, C1-C8 hydrocarbyl groups, C1-C8 alkoxy groups, C1-C8 carboxylate groups and C1-C8 carbamate groups;
- n is 1, 2 or 3;
- the or each L is an organic compound containing at least one lone pair of electrons;
- Q is a divalent radical of the formula YR5R6, wherein Y is a Group 14 atom, wherein R5 and R6 are each independently selected from among hydrogen and C1-C8 hydrocarbyl groups, and wherein R5 and R6 are not linked or are linked to form a saturated or unsaturated ring;
- E is a Lewis basic group having formula (i) or (ii) below:
- —C(R7)═Z1R8, (i)
- wherein R7 and R8 are each independently selected from among hydrogen and C1-C8 hydrocarbyl groups, and wherein R7 and R8 are not linked or are linked to form a saturated or unsaturated ring;
- and
- Z1 is a nitrogen atom or a phosphorus atom, which bonds to M;
- 6
- wherein
- Z2 is an oxygen atom, a sulphur atom or a selenium atom, which bonds to M;
- and
- R9, R10 and R11 are each independently selected from among hydrogen and C1-C8 hydrocarbyl groups, wherein no pair or one pair of substituents selected from R9, R10 and R11 are linked to form a saturated or unsaturated ring.
16 more elements
Dependencies are inferred from the claim text.