Polymer composition containing at least one middle molecular weight reactive polyisobutene
OwnerArno Lange, Stephan Huffer +4inventors
InventorsArno Lange, Stephan Huffer, Gabriele Lang, Helmut Mach, Hans Peter Rath, Eckhard Schauss
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Abstract
A polymer composition comprises at least one polyisobutene-containing component based on a medium molecular weight, reactive polyisobutene and at least one further polymer which is different therefrom.
Claims15
A polymer composition comprising:
- a) at least one polyisobutene-containing component selected from among medium molecular weight, reactive polyisobutene having a number average molecular weight Mn in the range from 5000 to 80000 dalton and a content of terminal double bonds of at least 50 mol %, derivatives of this medium molecular weight, reactive polyisobutene and mixtures thereof,
- b) at least one polymer which is different from a).
A composition as claimed in any of the preceding claims, wherein the component b) is selected from among elastomers having a glass transition temperature TG of not more than 0° C., preferably not more than −10° C.
A composition as claimed in any of the preceding claims, wherein the component b) is selected from among polymers which comprise, in polymerized/copolymerized form
- I) at least one styrene compound of the formula
- 4
- where
- R1 and R2 are each, independently of one another, hydrogen, C1-C30-alkyl, hydroxy, alkoxy or halogen, R3 is hydrogen or C1-C8-alkyl, and,
- II) if desired, at least one monomer which is different from I), is copolymerizable therewith and has at least one α,β-ethylenically unsaturated double bond.
A process for preparing a polyisobutene derivative by reaction of at least part of the double bonds present in a medium molecular weight, reactive polyisobutene in a single-stage or multistage functionalization selected from among:
- i) reaction with a compound containing at least one aromatic or heteroaromatic group in the presence of an alkylation catalyst to give a compound alkylated by polyisobutene, and, if desired, reaction in a further functionalization,
- ii) reaction with a peroxy compound to give an at least partially epoxidized polyisobutene,
- iii) reaction with an alkene which has an electrophilically substituted double bond in an ene reaction and, if desired, reaction in a further functionalization,
- iv) reaction with carbon monoxide and hydrogen in the presence of a hydroformylation catalyst to give an at least partially hydroformylated polyisobutene and, if desired, reaction in a further functionalization,
- v) reaction with hydrogen sulfide or a thiol in the presence of a catalyst to give a polyisobutene which is at least partially functionalized by thio groups,
- vi) reaction with a silane in the presence of a silylation catalyst to give a polyisobutene which is at least partially functionalized by silyl groups,
- vii) reaction with a halogen or a hydrogen halide in the presence of a-catalyst or electromagnetic radiation to give an at least partially halogenated polyisobutene,
- viii) reaction with a borane and subsequent oxidative cleavage to give an at least partially hydroxylated polyisobutene, and
- ix) reaction with SO3 or a compound capable of releasing SO3 to give a polyisobutene which is at least paretially functionalized by sulfo groups.
Dependencies are inferred from the claim text.