Hydrocarbon synthesis process using pressure swing reforming
AssigneeExxonMobil Research and Engineering Company
InventorFrank Hershkowitz
Life of this patent
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Abstract
The invention provides a method for producing liquid hydrocarbons by first generating in a pressure swing reformer a synthesis gas stream having a mole ratio of H2:CO greater than 2:1. Then, a portion of the hydrogen is separated to produce a synthesis gas stream having a mole ratio of H2:CO of about 2:1 which steam is then introduced into a hydrocarbon synthesis reactor for conversion to liquid products.
Claims12
An improvement in hydrocarbon synthesis processes using synthesis gas stream containing H2 and CO, the improvement comprising:
- (a) generating a synthesis gas stream in a pressure swing reformer whereby the synthesis gas stream contains greater than a 2:1 mole ratio of H2:CO;
- and
- (b) separating a portion of the hydrogen from the synthesis gas stream to provide a synthesis gas stream containing about a 2:1 mole ratio of H2:CO;
- (c) introducing the synthesis gas stream of step (b) into a hydrocarbon synthesis reactor for conversion to liquid products therein.
A synthesis gas and hydrocarbon conversion process comprising:
- (a) introducing a feed stream comprising a hydrocarbon and steam through a first end of a first zone containing bed packing materials and a steam reforming catalyst to produce a product synthesis gas stream at a first pressure having a ratio of H2:CO greater than 2:1;
- (b) passing at least a portion of the product to step (a) to a second zone containing bed packing materials, and transferring the sensible heat from the product to the packing materials;
- (c) removing substantially all of the product from said second zone;
- (d) introducing an oxygen-containing gas into the second end of said second zone;
- (e) contacting said oxygen-containing gas with a fuel and combusting said gas and fuel within said zones at a second pressure lower than the first pressure, thereby re-heating said first zone to reforming temperatures and creating a fluegas which exits through the first end of said first zone;
- (f) separating sufficient hydrogen from the product recovered in step (c) to produce a synthesis gas stream having a H2:CO ratio of about 2:1;
- and
- (g) introducing the synthesis gas of step (f) into a hydrocarbon synthesis reactor for conversion therein to liquid products.
Dependencies are inferred from the claim text.