Esterification of xanthophylls
AssigneeDsm IP Assets B.V.
InventorsMario D.T. Cordona, Gustavo Rodriguez
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Abstract
Lutein and zeaxanthin, the main carotenoids in marigold flowers, and capsanthin and capsorubin, the main carotenoids in red peppers are esterified mainly with C-18 fatty acids. The pigments were re-esterified without isolating them from the natural saponified extract using carboxylic acids in the range of C-1 to C-12 and their corresponding metallic salts in the presence of a catalyzing agent. Both the diester and monoester forms were obtained. It is expected that the pigment esters with a fatty acid of 12 or less carbons will have a better digestibility than the esters of xanthophylls in their natural state and better stability than the hydrolyzed xanthophylls. This will result in a better pigmentation capacity of the carotenoids for poultry or aquaculture.
Claims33
A process for the esterification of xanthophylls comprising:
- reacting an extract containing xanthophylls with a carboxylic acid having a carbon chain length between 1 to 12 in the presence of a catalyst;
- and
- continuously removing the water generated from the reaction to facilitate the transformation to xanthophyll esters;
- and
- collecting the xanthophyll ester product.
Dependencies are inferred from the claim text.