Catalyst composition for preparing olefin polymers
AssigneeIndustrial Technology Research Institute
InventorsJing-Cherng Tsai, Ming-Yuan Wu, Tung-Ying Hsieh, Yuh-Yuan Wei, Chao-Ying Yu
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Abstract
A catalyst composition for preparing olefin polymers. The catalyst composition includes a metallocene compound and an activating cocatalyst. In the metallocene compound, two cyclopentadienyl groups are bridged by X (carbon, silicon, germanium or tin) in a ring structure. The bite angle 0 formed by the two cyclopentadienyl rings and X is equal to or greater than 100 degrees. The obtained olefin polymer has high cycloolefin conversion and a high glass transition temperature. In addition, the catalyst composition can still maintain relatively high activity at high temperature reaction conditions.
Claims30
A catalyst composition for preparing an olefin polymer, comprising:
- (a) a metallocene compound represented by the formula (I)
- 13
- wherein
- R1 can be the same or different and is hydrogen, halogen, an alkyl, alkenyl, aryl, alkylaryl or arylalkyl group having from 1 to 20 carbon atoms, or two adjacent R1 groups can link together with the carbon atoms to which they are attached to form a saturated or unsaturated ring system having from 4 to 20 carbon atoms;
- R2 can be the same or different and has the same definition as R1;
- X is carbon, silicon, germanium, or tin;
- n is 2, 3 or 4;
- R3 and R4 can be the same or different and are hydrogen, halogen, an alkyl, alkenyl, aryl, alkylaryl or arylalkyl group having from 1 to 12 carbon atoms;
- M is a Group IVB transition metal with an oxidation state of +4;
- Y is the same or different and is independently an anionic ligand with a −1 valence;
- and
- the angle θ formed by the two cyclopentadienyl rings and X is equal to or greater than 100 degrees;
- (b) an activating cocatalyst of (1) an aluminoxane, (2) a mixture of AlR11R12R13 and a borate, or (3) a mixture of AlR11R12R13 and an aluminoxane, wherein R11, R12, and R13 are a C1-20 aliphatic group or a C6-10 aromatic group.
Dependencies are inferred from the claim text.