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US 2003/0199650 A1Published application
Bridged metal complexes for gas phase polymerizations
AssigneeBP Chemicals Limited
InventorsDavid D. Devore, David R. Neithamer
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Abstract
A gas phase olefin polymerization wherein the catalyst comprises a novel Group 4 transition metal complex containing a boron or aluminum bridging group containing a nitrogen containing group, especially an amido group.
Claims15
(New) an olefin polymerization process comprising contacting one or more olefin monomers under gas phase polymerization conditions with a catalyst composition comprising a metal complex corresponding to the following formula:
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- wherein:
- M is titanium, zirconium, or hafnium in the +4, +3, or +2 oxidation state;
- Y1 and Y2 are independently an anionic, cyclic or non-cyclic, π-bonded group, NR1, PR1;
- NR12 or PR12;
- Z is boron or aluminum;
- Q is a neutral, anionic or dianionic ligand group depending on the oxidation state of M;
- j is 1, 2 or 3 depending on the oxidation state of M and the electronic nature of Q;
- T independently each occurrence is:
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- wherein R1 is independently each occurrence hydrogen, a hydrocarbyl group, a tri(hydrocarbyl)silyl group, or a tri(hydrocarbyl)silylhydrocarbyl group, said R1 groups containing up to 20 atoms not counting hydrogen;
- R5 is R1 or N(R1)2;
- and
- two R1 groups together or one or more R1 groups together with R5 may optionally be joined to form a ring structure.
11 more elements
Dependencies are inferred from the claim text.