Use of cationically modified, particulate, hydrophobic polymers as an additive for rinsing, cleaning and impregnating agents for hard surfaces
OwnerDieter Boeckh, Ralf Nörenberg +5inventors
InventorsDieter Boeckh, Ralf Nörenberg, S?ouml;ren Hildebrandt, Bernhard Mohr, Holger Schöpke, Reinhold J Leyrer, J?uuml;rgen Huff
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Abstract
Use of cationically modified, particulate, hydrophobic polymers, the surface of which has been cationically modified by coating with cationic polymers, and the particle size of which is 10 nm to 100 μm, as additive to rinse, cleaning and impregnation compositions for hard surfaces, and rinse, cleaning and impregnation compositions which comprise the cationically modified, particulate, hydrophobic polymers.
Claims21
The use of cationically modified, particulate, hydrophobic polymers, the surface of which has been cationically modified by coating with cationic polymers, and the particle size of which is 10 nm to 100 μm, as additive to rinse, cleaning and impregnation compositions for hard surfaces.
A composition for the treatment of hard surfaces, which comprises
- (a) 0.05 to 40% by weight of cationically modified, particulate, hydrophobic polymers, the surface of which has been cationically modified by coating with cationic polymers, and the particle size of which is 10 nm to 100 μm,
- (b) 0 to 20% by weight of at least one water-soluble salt of Ca, Mg, Al, Zn and/or 0.01 to 30% by weight of at least one cationic surfactant and/or 0.01 to 15% by weight of at least one cationic polymer,
- (c) 0 to 80% by weight of at least one customary additive, such as acids or bases, inorganic builders, organic cobuilders, further surfactants, polymeric color transfer inhibitors, polymeric antiredeposition agents, soil release polymers, enzymes, complexing agents, corrosion inhibitors, waxes, silicone oils, light protection agents, dyes, solvents, hydrotropes, thickeners and/or alkanolamines and
- (d) water to make up to 100% by weight.
A composition in liquid or gel form for the care and cleaning of hard surfaces, which comprises
- (a) 0.1 to 30% by weight of particulate, hydrophobic polymers which contain, in copolymerized form, at least one group of anionic ethylenically unsaturated monomers, have been cationically modified by treatment with cationic polymers, have a particle size of from 10 nm to 100 μm and have been dispersed in water,
- (b) 0.05 to 20% by weight of an acid,
- (c) 0 to 30% by weight of at least one water-soluble salt of Mg, Ca, Zn or Al and/or of a cationic surfactant and/or 0.01 to 15% by weight of at least one cationic polymer,
- (d) 0 to 20% by weight of at least one other customary ingredient, such as perfume, further surfactants, silicone oil, light protection agents, dye, complexing agents, antiredeposition agent, soil release polyester, color transfer inhibitor, nonaqueous solvent, hydrotropic agent, thickener and/or alkanolamine and
- (e) water to make up to 100% by weight.
A cleaning and care formulation in liquid or gel form, which comprises
- (a) 0.05 to 30% by weight of cationically modified, particulate, hydrophobic polymers, the surface of which has been cationically modified by coating with cationic polymers, and the particle size of which is 10 nm to 100 μm,
- (b) 0.1 to 40% by weight of at least one nonionic or anionic surfactant,
- (c) 0 to 30% by weight of at least one water-soluble salt of Mg, Ca, Zn or Al and/or of a cationic surfactant and/or 0.01 to 15% by weight of at least one cationic polymer,
- (d) 0 to 10% by weight of at least one complexing agent,
- (e) 0 to 20% by weight of other customary ingredients, such as pH regulators, extenders, thickeners, solvents, hydrotropic agents, polycarboxylic acids, silicones, brighteners, perfume and/or dyes and
- (f) 0 to 90% by weight of water.
An acidic cleaning formulation in liquid or gel form, which comprises
- (a) 0.1 to 30% by weight of particulate, hydrophobic polymers which contain, in copolymerized form, at least one group of anionic ethylenically unsaturated monomers, have a particle size of from 10 nm to 100 μm and have been dispersed in water,
- (b) 0.05 to 20% by weight of an acid,
- (c) 0.1 to 30% by weight of at least one water-soluble cationic polymer,
- (e) 0 to 10% by weight of at least one complexing agent,
- (f) 0 to 20% by weight of other customary ingredients, such as pH regulators, extenders, surfactants, thickeners, solvents, hydrotropic agents, polycarboxylic acids, silicones, brighteners, perfume and/or dyes and
- (g) 0 to 90% by weight of water.
An acidic cleaning formulation in liquid or gel form which comprises
- (a) 0.5 to 25% by weight of particulate, hydrophobic polymers which contain, in copolymerized form, 25 to 60% by weight of an ethylenically unsaturated monomer containing at least one carboxylic acid group, have a particle size of from 10 nm to 100 μm and have been dispersed in water using an anionic emulsifier and/or an anionic protective colloid,
- (b) 0.01 to 40% by weight of at least one nonionic or anionic surfactant,
- (c) 0.01 to 20% by weight of at least one water-soluble or water-dispersible cationic polymer,
- (d) 0.1 to 30% by weight of at least one water-soluble salt of Mg, Ca, Zn or Al and/or of a cationic surfactant,
- (e) 0.1 to 20% by weight of at least one acid,
- (f) 0 to 10% by weight of at least one complexing agent,
- (g) 0 to 20% by weight of other customary ingredients, such as pH regulators, extenders, thickeners, solvents, hydrotropic agents, polycarboxylic acids, silicones, brighteners, perfume and/or dyes and
- (h) 0 to 90% by weight of water.
A solid cleaning formulation which comprises
- (a) 0.05 to 30% by weight of cationically modified, particulate, hydrophobic polymers, the surface of which has been cationically modified by coating with cationic polymers, and the particle size of which is 10 nm to 100 μm,
- (b) 0.1 to 40% by weight of at least one nonionic and/or anionic surfactant,
- (c) 0-10% by weight of a cationic polymer,
- (d) 0-20% by weight of a water-soluble salt of Mg, Ca, Zn or Al and/or of a cationic surfactant,
- (e) 0 to 80% by weight of an inorganic builder, extender and/or scouring agent,
- (f) 0 to 20% by weight of a complexing agent and/or organic cobuilder,
- (g) 0 to 10% by weight of other customary ingredients, such as brighteners, waxes, oils, perfume, corrosion inhibitors, bleaches, bleach activators, bleach catalysts, dyes and
- (h) water to 100%.
An afterrinse and impregnation formulation in liquid or gel form which comprises
- (a) 0.05 to 30% by weight of cationically modified, particulate, hydrophobic polymers, the surface of which has been cationically modified by coating with cationic polymers, and the particle size of which is 10 nm to 100 μm,
- (b) 0.1 to 30% by weight of at least one nonionic or anionic surfactant,
- (c) 0 to 10% by weight of at least one acid, preferably a carboxylic acid,
- (d) 0-10% by weight of a cationic polymer,
- (e) 0-20% by weight of a water-soluble salt of Mg, Ca, Zn or Al and/or of a cationic surfactant,
- (f) 0 to 10% by weight of other customary ingredients, such as thickeners, complexing agents, solvents, oils, waxes, hydrotropic agents, foam-suppressing agents, polycarboxylic acids, silicones, brighteners, perfume, dyes and
- (g) 0 to 90% by weight of water.
Dependencies are inferred from the claim text.