Electron donors, electron acceptors and adhesion promoters containing disulfide
AssigneeNational Starch and Chemical Investmnet Holding Corporation
InventorOsama M. Musa
Life of this patent
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AssigneeNational Starch and Chemical Investmnet Holding Corporation
InventorOsama M. Musa
Estimating the term…
Disclosed are compounds comprising both disulfide functionality and electron donor functionality or alkoxy siloxane functionality, and curable compositions comprising compounds comprising both disulfide functionality and electron donor functionality, or electron acceptor functionality, or alkoxy siloxane functionality.
A compound having the structure
A composition comprising a compound having the structure
A compound having the structure
A composition comprising a compound having the structure
Dependencies are inferred from the claim text.
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Having the sulfur atoms of the thio groups bound to acyclic carbon atoms of the carbon skeleton: the carbon skeleton being acyclic and saturated
Compounds having one or more C—Si linkages as well as one or more C—O—Si linkages: compounds having Si-O-C linkages
Acyclic or carbocyclic compounds
Acyclic, carbocyclic or heterocyclic compounds containing elements other than carbon, hydrogen, halogen
Term end not estimated
This invention relates to compounds containing electron donor, electron acceptor, or adhesion promoting functionality, and a disulfide functionality.
Curable compositions are used in the fabrication and assembly of semiconductor packages and microelectronic devices, such as in bonding integrated circuit chips to substrates, bonding circuit assemblies to printed wire boards, coating lead frames, underfilling the gap between chip and substrate, and encapsulating the chip and substrate assembly.
Substrates used in the fabrication of semiconductor packages can be metal, ceramic, or laminate. There are a number of electron donor/electron acceptor systems that are used in the industry, but curable compositions that in general have good performance may be deficient when used on one or more of these substrates. The addition of adhesion promoters or the use of curable resins that contain adhesion promoting capability would serve to correct this deficiency.
Resin A. 16
Silquest A-1310 (64.1 g, 0.26 mole, available from Witco) and 2-hydroxyethyl disulfide (20.0 g, 0.13 mole) were solvated in toluene (50 g) in a 500 mL three-necked flask equipped with a mechanical stirrer, condenser and nitrogen inlet/outlet. The reaction was placed under nitrogen, and dibutyltin dilaurate (0.07 g, 0.00011 mole) was added with stirring as the solution was heated to 80° C. The resulting mixture was heated for an additional three hours at 80° C. After the reaction was allowed to cool to room temperature, the solvent was removed in vacuo to give the product in 96% yield.
Resin B. 17