Abstract
Fluorescent maleimides of the formula I 1
wherein
R1 and R2 independently from each other stand for 2
wherein Q1 stands for hydrogen, halogen, phenyl, —E—C1-C8alkyl, —E-phenyl, wherein phenyl can be substituted up to three times with C1-C8alkyl, halogen, C1-C8alkoxy, diphenylamino, —CH═CH—Q2, wherein Q2 stands for phenyl, pyridyl, or thiophenyl, which can be substituted up to three times with C1-C8alkyl, halogen, C1-C8alkoxy, —CN, wherein E stands for oxygen or sulfur, and wherein R21 stands for C1-C8alkyl, phenyl, which can be substituted up to three times with C1-C4alkyl, C1-C4alkoxy, or dimethylamino, and R22 and R23 independently from each other stand for hydrogen, R21, C1-C8alkoxy, or dimethylamino,
or —NR4R5, wherein R4 and R5, independently from each other stand for hydrogen, phenyl, or C1-C8alkyl-carbonyl, or —NR4R5 stands for a five- or six-membered ring system, and R3 stands for allyl, 3
wherein Q3 stands for hydrogen, halogen, C1-C8alkoxy, or C1-C8alkyl-amido, unsubstituted or substituted C1-C8alkyl, unsubstituted or up to three times with halogen, —NH2, —OH, or C1-C8alkyl substituted phenyl,
and Z stands for a di- or trivalent radical selected from the group consisting of substituted or unsubstituted cyclohexylene, preferably 1,4-cyclohexylene, triazin-2,4,6-triyl, C1-C6alkylene, 1,5-naphthylene, 4
wherein
Z1, Z2 and Z3, independently from each other stand for cyclohexylene or up to three times with C1-C4alkyl substituted or unsubstituted phenylene, preferably unsubstituted or substituted 1,4-phenylene,
and wherein R6 and R7, independently from each other, stand for 5
n stands for 1, 2 or 3, and m stands for 1 or 2, with the proviso, that R1 and R2 not simultaneously stand for phenyl,
and its different uses such as in electroluminescent devices and as void detection compounds.