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US 2003/0166943 A1Published application
Oxadiazole derivative and its use as charge transport and light emitting material
AssigneeMerck Patent GmbH
InventorsPeer Kirsch, Alexander Hahn
Life of this patent
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Abstract
New oxadiazole derivatives comprising one or more identical or different recurring units of formula I 1 wherein W, M, w, m1, m2, p1, p2, and Y1 to Y4 are as defined herein are suitable for use in liquid crystalline mixtures, polymerizable and polymer materials.
Claims41
An oxadiazole compound comprising one or more identical or different recurring units of formula I
- 23
- wherein
- W is a straight chain or branched alkylene group with 1 to 22 C-atoms, which is unsubstituted or is mono- or polysubstituted by F, Cl, Br, I or CN, wherein one or more CH2 groups may optionally be replaced, in each case independently from one another, by —O—, —S—, —NH—, —NR0—, —CO—, —COO—, —OCO—, —OCO—O—, —S—CO—, —CO—S—, —CH═CH—, —CF═CF— or —C≡C— in such a manner that N, O and/or S atoms are not linked directly to one another;
- R0 is in each case independently H or alkyl with 1 to 12 C-atoms;
- M is, if occuring twice or more, independently of each other, a mesogenic or mesogenity supporting group;
- Y1 to Y4 are in each case independently of each other H, F, Cl or CN;
- w is in each case independently 0 or 1;
- m1, m2 are in each case independently and independently of each other 0 or 1, whereby m1+m2≧1;
- and
- p1, p2 are in each case independently and independently of each other 0 or 1, whereby p1+p2≧1;
- with the proviso that formula I does not include
- 2-styryl-5-trichloromethyl-oxadiazole, 2-styryl-5-tribromomethyl-oxadiazole, 2-(alkylstyryl)-5-trichloromethyl-oxadiazole, 2-(alkylstyryl)-5-tribromomethyl-oxadiazole ,2-(alkoxystyryl)-5-trichloromethyl-oxadiazole, 2-(alkoxystyryl)-5-tribromomethyl-oxadiazole, 2-(4-chlorostyryl)-5-trichloromethyl-oxadiazole, 2-(4-chlorostyryl )-5-tribromomethyl-oxadiazole, 2-(4-styrylstyryl)-5-trichloromethyl-oxadiazole, 2-(4-styrylstyryl)-5-tribromomethyl-oxadiazole, 2-(benzofuran-2-yl )-5-trichloromethyl-oxadiazole, and 2-(benzofuran-2-yl)-5-tribromomethyl-oxad iazole.
9 more elements
An oxadiazole compound according to cliam 1, wherein W is a bridging group of formula I3
- 28
- wherein
- Q1, Q2 are independently of each other —O—, —S—, —COO—, —OCO—, —CO— or a single bond;
- R3, R4 are independently of each other H, F, Cl, CN, alkyl with 1 to 6 C-atoms which is unsubstituted or mono- or polysubstituted by F, or alkoxy with 1 to 6 C-atoms, which is unsubstituted or mono- or polysubstituted by F, and
- v is 1 to 20.
2 more elements
Dependencies are inferred from the claim text.