Powdered thermosetting composition for coatings
OwnerLuc Moens, Nele Knoops +1inventors
InventorsLuc Moens, Nele Knoops, Daniel Maetens
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OwnerLuc Moens, Nele Knoops +1inventors
InventorsLuc Moens, Nele Knoops, Daniel Maetens
Estimating the term…
The present invention relates to powdered thermosetting compositions including a binder which comprises a carboxyl group containing amorphous isophthalic acid containing polyester, a carboxyl group containing aliphatic semi-crystalline polyester, an optional and different carboxyl group containing semi-crystalline polyester, at least 5 parts by weight, based on the total weight of the binder, of a specific glycidyl group containing acrylic copolymer and a curing agent having functional groups reactive with the polyesters' carboxyl groups. The powdered thermosetting compositions are useful for the preparation of powdered paints and varnishes which give semi-matt coatings having an outstanding flow, a remarkable weatherability and excellent mechanical properties.
Powdered thermosetting composition including a binder which comprises
Composition according to any of the preceding claims, wherein the carboxyl group containing semi-crystalline polyesters (b) and (c) both have an acid number (AN) from 10-50 mg KOH/g, a number averaged molecular weight (Mn) from 2200-17000, a fusion zone from 30-150° C., a glass transition temperature (Tg) from −50 to 50° C., a degree of crystallinity of at least 5 J/g and an ICI (cone/plate) viscosity at 175° C. from 5-20000 mPa.s.
Composition according to any of the preceding claims, wherein the glycidyl group containing acrylic copolymer consists of 10-90 mole % of a glycidyl group containing monomer selected from the group consisting of glycidyl acrylate, glycidyl methacrylate, methyl glycidyl acrylate, methyl glycidyl methacrylate, 3,4-epoxycyclohexylmethyl acrylate, 3,4-epoxycyclohexylmethyl methacrylate, acrylic glycidyl ether and mixtures thereof and 10-90 mole % of monomers copolymerisable with the glycidyl group containing monomers.
Composition according to any of the preceding claims, wherein the glycidyl group containing acrylic copolymer has an epoxy equivalent weight of 1.0 to 7.0 milliequivalent of epoxy/gram of polymer, a number averaged molecular weight (Mn) ranging from 1000 to 10000, a glass transition temperature (Tg) from 40-85° C. and an ICI (cone/plate) viscosity at 200° C. from 60-50000 mPa.s.
Composition according to any of the preceding claims, wherein the binder comprises, based on the total weight of the binder,
Composition according to any of the preceding claims, further comprising one or more additive(s) selected from the group consisting of catalysts, fillers, flow control agents, degassing agents, UV-light absorbers, light stabilizers, antioxidants and other stabilizers.
Composition according to any of the preceding claims, further comprising one or more dyes and/or pigments, such as metal oxides, metal hydroxides, metal powders, sulphides, sulphates, carbonates, silicates, carbon black, talc, china clay, barytes, iron blue, lead blue, organic reds and organic maroons.
Dependencies are inferred from the claim text.