Low ash, low phosphorus and low sulfur engine oils for internal combustion engines
AssigneeExxonMobil Research and Engineering Company
InventorsLiehpao O. Farng, Andrew Jackson, Willie A. Givens JR., Douglas E. Deckman, William H. Buck
Life of this patent
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Abstract
A lubricating composition for internal combustion engines especially useful with fuels having less than 350 ppm sulfur comprises a lubricating oil basestock, a boron containing ashless dispersant, a molybdenum containing friction reducing agent, a metal type detergent and zinc dithiophosphate.
Claims14
A lubricating composition comprising:
- (a) a major amount of a base oil of lubricating viscosity and having a sulfur content below about 300 ppm based on the weight of base oil;
- (b) about 0.5 wt % to about 10 wt % of a boron-containing ashless dispersant;
- (c) about 0.05 wt % to about 1.50 wt % of a molybdenum containing friction reducing additive;
- (d) about 0.05 wt % to about 5.0 wt % of at least one kind of metal-type detergent selected from the group consisting of sulfonates, phenates and salicylates;
- and
- (e) 0.10 wt % to 0.75 wt % of a zinc dithiophosphate.
In the method of combusting an ultra low sulfur fuel in an internal combustion engine lubricated with a lubricating composition, the improvement comprising using as the lubricating composition one comprising:
- (a) a major amount of a base oil of lubricating viscosity and having a sulfur content below about 300 ppm based on the weight of base oil;
- (b) about 0.5 wt % to about 10 wt % of a boron-containing ashless dispersant;
- (c) about 0.05 wt % to about 5.0 wt % of a molybdenum containing friction reducing additive;
- (d) about 0.05 wt % to about 5.0 wt % of at least one kind of metal-type detergent selected from the group consisting of sulfonates, phenates and salicylates;
- and
- (e) 0.10 wt % to 0.75 wt % of a zinc dialkyl dithiophosphate.
A lubricating oil composition comprising:
- (a) a major amount of an oil of lubricating viscosity and having a sulfur content below about 300 ppm sulfur;
- (b) about 0.5 wt % to about 10 wt % of a boron-containing polyisobutylene succinic ester-amide ashless dispersant;
- (c) about 0.05 wt % to about 1.50 wt % of a trinuclear molybdenum compound having the formula Mo3S7(dtc)4, Mo3S4(dtc)4 and mixture thereof where dtc represents diorganodithiocarbamate ligands;
- (d) about 0.05 wt % to about 5.0 wt % of at least one metal-type detergent selected from the group consisting of calcium, magnesium and barium sulfonates, phenates and salicylates;
- and
- (e) 0.10 wt % to 0.75 wt % of a zinc dithiophosphate wherein the alkyl groups are the same or different alkyl groups of from 3 to 20 carbon atoms, said composition having a sulfur content of less than 0.18 wt %, a phosphorous content of less than 0.048 wt % and a sulfated ash of less than 0.5 wt %.
A method for reducing friction and the wear in an oil lubricated engine combusting an ultra low sulfur fuel, the method comprising lubricating the engine under conditions of use with a lubricating composition comprising:
- a major amount of an oil of lubricating viscosity having a sulfur content below about 300 ppm sulfur;
- about 0.5 wt % to about 10 wt % of a boron-containing ashless dispersant;
- about 0.05 wt % to about 1.5 wt % of a molybdenum containing friction reducing additive;
- about 0.05 wt % to about 5.0 wt % of at least one kind of metal-type detergent selected from the group consisting of sulfonates, phenates and salicylates;
- and
- wt % to 0.75 wt % of a zinc dithiophosphate.
Dependencies are inferred from the claim text.