Use of a composition in stereolithography
AssigneeQinetiq Limited
InventorsJohn W Goodby, Alan W Hall, Keith M Blackwood, Paul E Y Milne, Andrew G Biggs, Ryan M Heath, Robert W Bannister
Life of this patent
Estimating the term…
Abstract
The use of a compound of formula (A), which comprises a group of sub-formula (I) where R1, R2, R3, R4, R5, R6, X1 and Y1 are various specified organic groups wherein at least one of said groups has sufficient electron whitdrawing properties to activate the multiple bonds to polymerisation, in a stereolithographic composition. Stereolithographic applications of these compounds are also described and claimed. 1
Claims33
The use of a compound of formula (A), which comprises a group of sub-formula (I)
- 35
- where R1 is CRa′ where Ra′ is hydrogen or alkyl, and R6 is a bond, or R1 and R6 together form an electron withdrawing group;
- R2 and R3 are independently selected from (CR7R8) , or a group CR9R10, CR7R8CR9R10 or CR9R10CR7R8 where n is 0, 1 or 2, R7 and R8 are independently selected from hydrogen or alkyl, and either one of R9 or R10 is hydrogen and the other is an electron withdrawing group, or R9 and R10 together form an electron withdrawing group, and R4 and R5 are independently selected from CH or CR11 where R11 is an electron withdrawing group;
- the dotted lines indicate the presence or absence of a bond, and X1 is a group CX2X3 where the dotted line bond to which it is attached is absent and a group CX2 where the dotted line bond to which it is attached is present, Y1 is a group CY2Y3 where the dotted line bond to which it is attached is absent and a group CY2 where the dotted line bond to which it is attached is present, and X2, X3, Y2 and Y3 are independently selected from hydrogen and fluorine;
- provided that at least one of (a) R1 and R6 or (b) R2 and R3 or (c) R4 and R5 includes an electron withdrawing group which is able to activate a cyclopolymerization reaction under the influence of radiation used in a stereolithographic process optionally in the presence of a photoinitiator;
- in a stereolithographic composition.
The use according to any one of the preceding claims wherein at least R1 and R6 form an electron withdrawing group.
The use according to any one of the preceding claims wherein in the group of sub-formula (I), X2, X3, Y2 and Y3 are all hydrogen.
The use according to any one of the preceding claims for the formation of semi-conductor features.
A stereolithographic composition comprising a compound as defined in any one of the preceding claims, a photoinitiator compound, and at least one further component selected from a filler, extender, stabiliser, radiation absorber, polariser, solvent or other monomers.
Dependencies are inferred from the claim text.