Pressure-sensitive adhesives exhibiting an improved shear strength at elevated temperatures
AssigneeBayer MaterialScience AG
InventorThomas P. Abend
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AssigneeBayer MaterialScience AG
InventorThomas P. Abend
Estimating the term…
The invention relates to pressure-sensitive adhesive layers produced from aqueous dispersions consisting of polymers with isocyanate-reactive groups and of surface-deactivated solid isocyanates whose shear strength can be improved by elevated temperatures. In a first step, a property profile results after water is removed by drying at drying temperatures (a) ranging from 20° C. to 95° C. Said property profile can be influenced in a second step, by a thermal treatment (b) on the single or double-sided-pressure-sensitive adhesive tape or transfer tape or on the finished bonding, in order to improve shear strength (or rather to render it less inclined to creeping) with an acceptable loss of surface adhesiveness. The duration of the thermal treatment (b) ranges from a m of 5 seconds at 135° C. (or higher temperatures) to a maximum of 30 minutes at 90° C. (measured in the layer). The maximum temperature of the thermal treatment (b) exceeds the drying temperature (a) by at least 40° C. The cross-linked pressure-sensitive adhesive layers are used in high-performance adhesives, which are creep-resistant at high temperatures, in adhered joints in assembling and manufacturing processes, in adhesive tape configurations used in the field of fastenings, which can be statically subjected to stresses. They can also be used for fastening bondings with increased temperature stability and shear strength.
Process for the preparation of a pressure-sensitive adhesive layer and for increasing its shear strength, comprising the steps
Process for increasing the shear strength of a pressure-sensitive adhesive layer, especially having a loop tack of at least 2 N/inch, prepared from an aqueous dispersion containing at least one isocyanate-reactive polymer and at least one surface-deactivated polyisocyanate, characterised in that the pressure-sensitive adhesive layer is exposed to a temperature in the range from 60° C. to 200° C., preferably from 90° C. to 180° C., the shear strength of the resulting adhesive bond being increased by at least 10% as compared with the shear strength of the pressure-sensitive adhesive layer prior to the heat treatment (b).
Use of an aqueous dispersion or solution containing at least one isocyanate-reactive polymer and a solid surface-deactivated polyisocyanate in the production of a pressure-sensitive adhesive layer having a loop tack of at least 2 N/inch.
Dependencies are inferred from the claim text.