Polyester composition
AssigneeHitech Polymers Inc.
InventorGerald W. Miller
Life of this patent
Estimating the term…
Abstract
Polyester compositions useful to improve the impact and heat distortion properties of polyethylene terephthalate, providing the polyethylene terephthalate with both high notched Izod properties and high heat distortion properties. The composition is the reaction of a terpolymer of ethylene, an acrylate or a methacrylate, and glycidyl methacrylate with polyethylene terephthalate in the presence of at least one elastomer such as a copolymer of ethylene and 1-octene, and polypropylene, an ethylene propylene copolymer, polybutyleneterephthalate, polycyclohexanedimethanolterephthalate, or mixtures thereof, having a melt flow of about 6 to about 15 g/10 min. The product has a notched Izod value of at least about 4 ft. lbs/in and a heat distortion temperature of about 150° C. to about 190° C.
Claims15
A polyester composition comprising the reaction product of:
- a. about 50 to about 90 wt % of polyethylene terephthalate, having an intrinsic viscosity of 0.5 to about 1.2 dl/g;
- b. about 3 to about 20 wt % of a terpolymer of ethylene, methylacrylate or acrylate, and glycidylmethacrylate, having about 8 to about 35% glycidylmethacrylate component and a melt flow of about 3 to about 20 g/10 min;
- c. about 5 to about 40 wt % of an ethylene copolymer, with a melt flow of about 0.1 to about 10 g/10 min;
- and
- d. about 2 to about 25 wt % of polypropylene, an ethylene propylene copolymer, polybutyleneterephthalate, polycyclohexanedimethanolterephthalate, or mixtures thereof, having a melt flow of about 6 to about 15 g/10 min,
- wherein the product has a notched Izod value of at least about 4 ft. lbs/in and a heat distortion temperature of about 150° C. to about 190° C.
A composition comprising about 10 to about 60 wt % of reinforcing fibers or fillers and a polyester composition comprising the reaction product of:
- a. about 50 to about 90 wt % of polyethylene terephthalate, having an intrinsic viscosity of 0.5 to about 1.2 dl/g;
- b. about 3 to about 20 wt % of a terpolymer of ethylene, methylacrylate or acrylate, and glycidylmethacrylate, having about 8 to about 35% glycidylmethacrylate component and a melt flow of about 3 to about 20 g/10 min;
- c. about 5 to about 40 wt % of an ethylene copolymer, with a melt flow of about 0.1 to about 10 g/10 min;
- and
- d. about 2 to about 25 wt % of polypropylene, an ethylene propylene copolymer, polybutyleneterephthalate, polycyclohexanedimethanolterephthalate, or mixtures thereof, having a melt flow of about 6 to about 15 g/10 min,
- wherein the product has a notched Izod value of at least about 4 ft. lbs/in and a heat distortion temperature of about 150° C. to about 190° C.
A polyester composition comprising the reaction product of:
- a. about 70 to about 85 wt % of polyethylene terephthalate with an intrinsic viscosity of about 0.8 to about 1 dl/g;
- b. about 3 to about 10 wt % of a terpolymer of ethylene, a methacrylate or an acrylate, and glycidyl methacrylate, having about 8 to about 35% glycidylmethacrylate component and a melt flow of about 3 to about 20 g/10 min;
- c. about 5 to about 25 wt % of an ethylene-1-octene copolymer with a melt flow of about 0.1 to about 10 g/10 min;
- and
- d. 2 to about 10 wt % of a copolymer of propylene with about 3 to about 6 wt % ethylene content, polybutyleneterephthalate, polycyclohexanedimethanol-terephthalate, or mixtures thereof having a melt flow of about 6 to about 15 g/10 min;
- wherein the product has a notched Izod value of at least about 4 ft. lbs/in and a heat distortion temperature of about 150° C. to about 190° C.
Dependencies are inferred from the claim text.