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US 2003/0150066 A1Published application
Dyeing composition containing a para-aminophenol or para-phenylenediamine compound substituted with a silane radical
AssigneeL'oreal
InventorHerve Richard
Life of this patent
Estimating the term…
Abstract
A dyeing composition comprising at least one oxidation base chosen from para-aminophenol and para-phenylenediamine compounds substituted with a silane radical, and the dyeing method using this composition are disclosed. This composition is, for example, useful for dyeing keratinous fibres. The para-aminophenol and para-phenylenediamine compounds substituted with a silane radical are also disclosed.
Claims24
A dyeing composition, comprising at least one oxidation base chosen from compounds corresponding to the following formula (I) and the corresponding cosmetically acceptable salts thereof:
- 17
- wherein:
- A is chosen from OH and NH2;
- R1 and R2, which may be identical or different, are chosen from hydrogen, linear and branched C1-C8 alkyl radicals, C1-C6 hydroxyalkyl radicals, and —Y—B radicals;
- R1 and R2 may form, together with the nitrogen atom to which they are attached, a 4- to 7-membered heterocycle, optionally substituted with at least one group chosen from C1-C3 alkyls, OH, NH2 and Z—B radicals;
- provided that when A is OH, then R1 and R2 are each hydrogen;
- R3 and R4, which may be identical or different, are chosen from hydrogen, C1-C4 alkyl radicals, C1-C4 alkoxy radicals, halogen atoms, and —Z—B radicals;
- Y is chosen from saturated and unsaturated, linear and branched C1-C8 hydrocarbon chains that may include at least one hetero atom chosen from O, S, and NR, wherein R is chosen from hydrogen and C1-C4 alkyl radicals;
- Z is chosen from a covalent bond, and saturated and unsaturated, linear and branched C1-C8 hydrocarbon chains that may include at least one hetero atom chosen from O, S, and NR′, wherein R′ is chosen from hydrogen, C1-C4 alkyl radicals, O—Y radicals, and NR″—Y radicals, wherein R″ is chosen from hydrogen and C1-C4 alkyl radicals;
- B is chosen from —SiR5R6R7 groups, wherein R5, R6, and R7, which may be identical or different, are chosen C1-C4 alkyl and phenyl radicals;
- provided that at least one of the groups R1, R2, R3, and R4 is chosen from —Y'B and —Z—B.
8 more elements
A method for oxidation dyeing of keratinous fibres comprising applying to the keratinous fibres a composition comprising at least one oxidation base chosen from compounds corresponding to the following formula (I) and the corresponding cosmetically acceptable salts thereof:
- 18
- wherein:
- A is chosen from OH and NH2;
- R1 and R2, which may be identical or different, are chosen from hydrogen, linear and branched C1-C8 alkyl radicals, C1-C6 hydroxyalkyl radicals, and —Y—B radicals;
- R1 and R2 may form, together with the nitrogen atom to which they are attached, a 4- to 7-membered heterocycle, optionally substituted with at least one group chosen from C1-C3 alkyls, OH, NH2 and Z—B radicals;
- provided that when A is OH, then R1 and R2 are each hydrogen;
- R3 and R4, which may be identical or different, are chosen from hydrogen, C1-C4 alkyl radicals, C1-C4 alkoxy radicals, halogen atoms, and —Z—B radicals;
- Y is chosen from saturated and unsaturated, linear and branched C1-C8 hydrocarbon chains that may include at least one hetero atom chosen from O, S, and NR, wherein R is chosen from hydrogen and C1-C4 alkyl radicals;
- Z is chosen from a covalent bond, and saturated and unsaturated, linear and branched C1-C8 hydrocarbon chains that may include at least one hetero atom chosen from O, S, and NR′, wherein R′ is chosen from hydrogen, C1-C4 alkyl radicals, O—Y radicals, and NR″—Y radicals, wherein R″ is chosen from hydrogen and C1-C4 alkyl radicals;
- B is chosen from —SiR5R6R7 groups, wherein R5, R6, and R7, which may be identical or different, are chosen C1-C4 alkyl and phenyl radicals;
- provided that at least one of the groups R1, R2, R3, and R4 is chosen from —Y—B and —Z—B, in the presence of at least one oxidizing agent.
8 more elements
A multi-compartment device or multi-compartment dyeing kit comprising a first compartment comprising a composition comprising at least one oxidation base chosen from compounds corresponding to the following formula (I) and the corresponding cosmetically acceptable salts thereof:
- 19
- wherein:
- A is chosen from OH and NH2;
- R1 and R2, which may be identical or different, are chosen from hydrogen, linear and branched C1-C8 alkyl radicals, C1-C6 hydroxyalkyl radicals, and —Y—B radicals;
- R1 and R2 may form, together with the nitrogen atom to which they are attached, a 4- to 7-membered heterocycle, optionally substituted with at least one group chosen from C1-C3 alkyls, OH, NH2 and Z—B radicals;
- provided that when A is OH, then R1 and R2 are each hydrogen;
- R3 and R4, which may be identical or different, are chosen from hydrogen, C1-C4 alkyl radicals, C1-C4 alkoxy radicals, halogen atoms, and —Z—B radicals;
- Y is chosen from saturated and unsaturated, linear and branched C1-C8 hydrocarbon chains that may include at least one hetero atom chosen from O, S, and NR, wherein R is chosen from hydrogen and C1-C4 alkyl radicals;
- Z is chosen from a covalent bond, and saturated and unsaturated, linear and branched C1-C8 hydrocarbon chains that may include at least one hetero atom chosen from O, S, and NR′, wherein R′ is chosen from hydrogen, C1-C4 alkyl radicals, O—Y radicals, and NR″—Y radicals, wherein R″ is chosen from hydrogen and C1-C4 alkyl radicals;
- B is chosen from —SiR5R6R7 groups, wherein R5, R6, and R7, which may be identical or different, are chosen C1-C4 alkyl and phenyl radicals;
- provided that at least one of the groups R1, R2, R3, and R4 is chosen from —Y—B and —Z—B, and
- a second compartment comprising an oxidizing composition.
9 more elements
A coloured product obtained by oxidation of a composition comprising at least one oxidation base chosen from compounds corresponding to the following formula (I) and the corresponding cosmetically acceptable salts thereof:
- 20
- wherein:
- A is chosen from OH and NH2;
- R1 and R2, which may be identical or different, are chosen from hydrogen, linear and branched C1-C8 alkyl radicals, C1-C6 hydroxyalkyl radicals, and —Y—B radicals;
- R1 and R2 may form, together with the nitrogen atom to which they are attached, a 4- to 7-membered heterocycle, optionally substituted with at least one group chosen from C1-C3 alkyls, OH, NH2 and Z—B radicals;
- provided that when A is OH, then R1 and R2 are each hydrogen;
- R3 and R4, which may be identical or different, are chosen from hydrogen, C1-C4 alkyl radicals, C1-C4 alkoxy radicals, halogen atoms, and —Z—B radicals;
- Y is chosen from saturated and unsaturated, linear and branched C1-C8 hydrocarbon chains that may include at least one hetero atom chosen from O, S, and NR, wherein R is chosen from hydrogen and C1-C4 alkyl radicals;
- Z is chosen from a covalent bond, and saturated and unsaturated, linear and branched C1-C8 hydrocarbon chains that may include at least one hetero atom chosen from O, S, and NR′, wherein R′ is chosen from hydrogen, C1-C4 alkyl radicals, O—Y radicals, and NR″—Y radicals, wherein R″ is chosen from hydrogen and C1-C4 alkyl radicals;
- B is chosen from —SiR5R6R7 groups, wherein R5, R6, and R7, which may be identical or different, are chosen C1-C4 alkyl and phenyl radicals;
- provided that at least one of the groups R1, R2, R3, and R4 is chosen from —Y—B and —Z—B.
8 more elements
A method of manufacturing a coloured product comprising oxidizing a composition comprising at least one oxidation base chosen from compounds corresponding to the following formula (I) and the corresponding cosmetically acceptable salts thereof:
- 21
- wherein:
- A is chosen from OH and NH2;
- R1 and R2, which may be identical or different, are chosen from hydrogen, linear and branched C1-C8 alkyl radicals, C1-C6 hydroxyalkyl radicals, and —Y—B radicals;
- R1 and R2 may form, together with the nitrogen atom to which they are attached, a 4- to 7-membered heterocycle, optionally substituted with at least one group chosen from C1-C3 alkyls, OH, NH2 and Z—B radicals;
- provided that when A is OH, then R1 and R2 are each hydrogen;
- R3 and R4, which may be identical or different, are chosen from hydrogen, C1-C4 alkyl radicals, C1-C4 alkoxy radicals, halogen atoms, and —Z—B radicals;
- Y is chosen from saturated and unsaturated, linear and branched C1-C8 hydrocarbon chains that may include at least one hetero atom chosen from O, S, and NR, wherein R is chosen from hydrogen and C1-C4 alkyl radicals;
- Z is chosen from a covalent bond, and saturated and unsaturated, linear and branched C1-C8 hydrocarbon chains that may include at least one hetero atom chosen from O, S, and NR′, wherein R′ is chosen from hydrogen, C1-C4 alkyl radicals, O—Y radicals, and NR″—Y radicals, wherein R″ is chosen from hydrogen and C1-C4 alkyl radicals;
- B is chosen from —SiR5R6R7 groups, wherein R5, R6, and R7, which may be identical or different, are chosen C1-C4 alkyl and phenyl radicals;
- provided that at least one of the groups R1, R2, R3, and R4 is chosen from —Y—B and —Z—B.
8 more elements
At least one entity chosen from compounds of formula (I) and cosmetically acceptable salts thereof:
- 22
- wherein:
- A is chosen from OH and NH2;
- R1 and R2, which may be identical or different, are chosen from hydrogen, linear and branched C1-C8 alkyl radicals, C1-C6 hydroxyalkyl radicals, and —Y—B radicals;
- R1 and R2 may form, together with the nitrogen atom to which they are attached, a 4- to 7-membered heterocycle, optionally substituted with at least one group chosen from C1-C3 alkyls, OH, NH2 and Z—B radicals;
- provided that when A is OH, then R1 and R2 are each hydrogen;
- R3 and R4, which may be identical or different, are chosen from hydrogen, C1-C4 alkyl radicals, C1-C4 alkoxy radicals, halogen atoms, and —Z—B radicals;
- Y is chosen from saturated and unsaturated, linear and branched C1-C8 hydrocarbon chains that may include at least one hetero atom chosen from O, S, and NR, wherein R is chosen from hydrogen and C1-C4 alkyl radicals;
- Z is chosen from a covalent bond, and saturated and unsaturated, linear and branched C1-C8 hydrocarbon chains that may include at least one hetero atom chosen from O, S, and NR′, wherein R′ is chosen from hydrogen, C1-C4 alkyl radicals, O—Y radicals, and NR″—Y radicals, wherein R″ is chosen from hydrogen and C1-C4 alkyl radicals;
- B is chosen from —SiR5R6R7 groups, wherein R5, R6, and R7, which may be identical or different, are chosen C1-C4 alkyl and phenyl radicals;
- provided that at least one of the groups R1, R2, R3, and R4 is chosen from —Y—B and —Z—B.
8 more elements
A composition for dyeing keratinous fibres comprising at least one oxidation base chosen from compounds corresponding to the following formula (I) and the corresponding cosmetically acceptable salts thereof:
- 23
- wherein:
- A is chosen from OH and NH2;
- R1 and R2, which may be identical or different, are chosen from hydrogen, linear and branched C1-C8 alkyl radicals, C1-C6 hydroxyalkyl radicals, and —Y—B radicals;
- R1 and R2 may form, together with the nitrogen atom to which they are attached, a 4- to 7-membered heterocycle, optionally substituted with at least one group chosen from C1-C3 alkyls, OH, NH2 and Z—B radicals;
- provided that when A is OH, then R1 and R2 are each hydrogen;
- R3 and R4, which may be identical or different, are chosen from hydrogen, C1-C4 alkyl radicals, C1-C4 alkoxy radicals, halogen atoms, and —Z—B radicals;
- Y is chosen from saturated and unsaturated, linear and branched C1-C8 hydrocarbon chains that may include at least one hetero atom chosen from O, S, and NR, wherein R is chosen from hydrogen and C1-C4 alkyl radicals;
- Z is chosen from a covalent bond, and saturated and unsaturated, linear and branched C1-C8 hydrocarbon chains that may include at least one hetero atom chosen from O, S, and NR′, wherein R′ is chosen from hydrogen, C1-C4 alkyl radicals, O—Y radicals, and NR″—Y radicals, wherein R″ is chosen from hydrogen and C1-C4 alkyl radicals;
- B is chosen from —SiR5R6R7 groups, wherein R5, R6, and R7, which may be identical or different, are chosen C1-C4 alkyl and phenyl radicals;
- provided that at least one of the groups R1, R2, R3, and R4 is chosen from —Y—B and —Z—B;
- and the composition being effective in dyeing keratinous fibres.
9 more elements
A method for dyeing keratinous fibres comprising applying to the keratinous fibres a composition comprising at least one oxidation base chosen from compounds corresponding to the following formula (I) and the corresponding cosmetically acceptable salts thereof:
- 24
- wherein:
- A is chosen from OH and NH2;
- R1 and R2, which may be identical or different, are chosen from hydrogen, linear and branched C1-C8 alkyl radicals, C1-C6 hydroxyalkyl radicals, and —Y—B radicals;
- R1 and R2 may form, together with the nitrogen atom to which they are attached, a 4- to 7-membered heterocycle, optionally substituted with at least one group chosen from C1-C3 alkyls, OH, NH2 and Z—B radicals;
- provided that when A is OH, then R1 and R2 are each hydrogen;
- R3 and R4, which may be identical or different, are chosen from hydrogen, C1-C4 alkyl radicals, C1-C4 alkoxy radicals, halogen atoms, and —Z—B radicals;
- Y is chosen from saturated and unsaturated, linear and branched C1-C8 hydrocarbon chains that may include at least one hetero atom chosen from O, S, and NR, wherein R is chosen from hydrogen and C1-C4 alkyl radicals;
- Z is chosen from a covalent bond, and saturated and unsaturated, linear and branched C1-C8 hydrocarbon chains that may include at least one hetero atom chosen from O, S, and NR′, wherein R′ is chosen from hydrogen, C1-C4 alkyl radicals, O—Y radicals, and NR″—Y radicals, wherein R″ is chosen from hydrogen and C1-C4 alkyl radicals;
- B is chosen from —SiR5R6R7 groups, wherein R5, R6, and R7, which may be identical or different, are chosen C1-C4 alkyl and phenyl radicals;
- provided that at least one of the groups R1, R2, R3, and R4 is chosen from —Y—B and —Z—B.
8 more elements
A dyeing composition, comprising at least one oxidation base chosen from para-phenylenediamine compounds substituted with a silane radical and para-aminophenol compounds substituted with a silane radical.
Dependencies are inferred from the claim text.