Curable composition
AssigneeVantico Inc.
InventorsChristoph Rickert, Francois Turpin, Jacques Francois, Mireille Tena
Life of this patent
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Abstract
Powder coating compositions comprise a binder selected from carboxyl-group-containing polyesters, carboxyl-group-containing poly(meth)acrylates and mixtures of the said substances, and one or more novel epoxy compounds.
Claims15
A powder coating composition comprising a binder selected from carboxyl-group-containing polyesters, carboxyl-group-containing poly(meth)acrylates and mixtures of the said substances, and one or more epoxy compounds, wherein the epoxy compounds comprise at least one compound of formula (I) that is solid at 25° C.:
- 15
- wherein
- A corresponds to a group of formula (II), (III), (IV) or (VI):
- 16
- in which
- B is an x-valent organic radical that is derived from a polyol having x or more hydroxyl groups by the removal of x hydroxyl groups;
- E is a (2x)-valent organic radical that is derived from a polyol having (2×) or more hydroxyl groups by the removal of (2×) hydroxyl groups;
- and
- D is a (y+2z)-valent radical that is derived from a polyol having (y+2z) or more hydroxyl groups by the removal of (y+2z) hydroxyl groups;
- R1 and R5 are each independently of the other hydrogen, halogen, C1-C4alkyl or C1-C4alkoxy or are together a methylene group;
- and
- R2, R3, R4,
- R6, R7, R8
- and R9 are each independently of the others hydrogen, halogen, C1-C4alkyl or C1-C4alkoxy;
- and
- x is an integer of at least 3;
- y is an integer from 1 to (x−1) and
- z is (x−y).
A process for the preparation of a compound of formula (I) wherein
- A corresponds to a group of formula (II),
- B corresponds to an x-valent organic radical that is derived from a hydroxyl compound having x or more hydroxyl groups, and
- x corresponds to an integer of at least 1,
- which comprises the transesterification of a cyclohexene-3-carboxylic acid ester with an alcohol of formula B(OH)x, wherein x corresponds to an integer of at least 1, in the presence of LiNH2, with continuous removal from the reaction mixture of the alcohol freed from the cyclohexene-3-carboxylic acid ester, the transesterification being followed by the epoxidation of the carbon double bond(s) of the resulting transesterification product.
Dependencies are inferred from the claim text.