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US 2003/0148916 A1Published application
Antioxidants for the stabilization of formulations comprising surfactants
OwnerDietmar Huglin, Erich Kramerinventors
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Abstract
The invention relates to cleaning compositions comprising (a1) a phenolic antioxidant of the formula (1) and/or (2); and/or (a2) an antioxidant of the formula (3); and (b) a surfactant comprising a long alkyl or alkenyl chain. The antioxidants used according to the invention have excellent reactivity, good stability to hydrolysis, particularly in an alkaline medium, and, because of their solubility, can be easily incorporated into the soap formulations.
Claims24
A cleaning composition comprising
- (a1) a phenolic antioxidant of the formula
- 55
- (a2) an antioxidant of the formula
- 56
- in which in the formulae (1), (2) and (3)
- R1 is hydrogen;
- C1-C22 alkyl;
- C1-C22 alkylthio;
- C5-C12 cycloalkyl;
- phenyl;
- or C7-C9 phenylalkyl;
- R2 is C1-C22 alkyl;
- C5-C12 cycloalkyl;
- phenyl;
- C7-C9 phenylalkyl;
- or —SO3M;
- Q is —CmH2m—;
- 57
- —CmH2m—NH;
- a radical of the formula
- 58
- T is —CnH2n—;
- —(CH2)n—CH2—;
- 59
- or a radical of the formula
- 60
- V is —O—;
- or —NH—;
- a is 0;
- 1;
- or 2;
- b, c and d independently of one another are 0;
- or 1;
- e and f independently of one another are an integer from 1 to 3;
- and
- m, n and p independently of one another are an integer from 1 to 3;
- when e is 1,
- R3 is hydrogen;
- M;
- C1-C22 alkyl;
- C5-C12 cycloalkyl;
- C1-C22 alkylthio;
- C2-C22 alkenyl;
- C1-C18 phenylalkyl;
- a radical of the formula
- 61
- where,
- when R3 is C1-C22 alkyl, b=0;
- or Q is a radical of the formula (1a) or (1b);
- g is 0 or 1;
- M is hydrogen;
- alkali metal;
- or ammonium;
- when e is 2,
- R3 is a direct bond;
- —CH2—;
- 62
- —O—;
- or —S—;
- when e is 3,
- R3 is a radical of the formula
- 63
- where,
- when R3 is a radical of the formula (1k), c=1;
- and;
- R4 and R5 independently of one another are hydrogen;
- or C1-C22alkyl;
- and
- (b) a surfactant comprising a long alkyl or alkenyl chain.
66 more elements
Dependencies are inferred from the claim text.