An optical glass for a prism, which comprises, by mol %, 60 to 85% of SiO2, 5 to 20% of B2O3, 0 to 3% of Al2O3, 0 to 3% of Li2O, 5 to 20% of Na2O, 0 to 5% of K2O, the total content of Li2O+Na2O+K2O being 6 to 20%, 0 to 5% of MgO, 0 to 10% of CaO, 0 to 10% of SrO, 0 to 10% of BaO and 0 to 10% of ZnO, the total content of MgO+CaO+SrO+BaO+ZnO being 0.1 to 15%, which substantially contains no PbO, and wherein the absolute value of KΔt represented by the relational expression (I),
- 6 K Δ t = [ ( specific heat × specific gravity ) / thermal conductivity ] × Young ' s modulus × thermal expansion coefficient × ( 1 - Poisson ' s ratio ) × photoelastic constant ( I )
- is less than 3,000×10−2 m·s/(g·K).