Dye mixture of water-soluble fiber-reactive azo dyes, method for the production and use thereof
AssigneeDyStar Textifarben GmbH & Co. Deutschland KG
InventorsJoachim Steckelberg, Werner Russ
Life of this patent
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Abstract
Dye mixtures including one or more azo dyes of the general formula (1) and one or more azo dyes of the general formula (2) 1 are prepared and used for dyeing or printing hydroxyl- and/or carboxamido-containing material, preferably fiber material.
Claims8
A dye mixture comprising one or more azo dyes of the general formula (1) and one or more azo dyes of the general formula (2)
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- where
- M is a hydrogen atom, an ammonium ion or the equivalent of an alkali or alkaline earth metal,
- X1 is fluoro, chloro, alkoxy, hydroxyl, cyanamide, amino, anilino, anilinesulfonic acid, anilinedisulfonic acid, toluidine, anisole, or an unsubstituted or hydroxyl-, sulfo- or sulfato-substituted alkylamino,
- X2 has any of the meanings of X1
- Y1 and Y2 are each ethenyl or a moiety of the formula CH2CH2Z, where
- Z is a moiety that is eliminable by the action of alkali,
- R1, R2, R3, R4, R5 and R6 are independently hydrogen, alkyl, alkoxy, sulfo, hydroxyl, cyano, chloro or bromo,
- A is hydrogen or C1-C6-alkyl, with or without sulfo, hydroxyl or sulfato substitution or aniline with or without sulfo or halogen substitution,
- B is hydrogen, alkyl, CH 2CH2SO2Y, alkyl with or without SO2Y, —OCH2CH2SO2Y or —SO3M substitution or phenyl with or without substitution by up to three substituents selected for example from the group consisting of alkyl, alkoxy, sulfo, hydroxyl, cyano, chloro, bromo and SO2Y, where M and Y are each as defined above,
- A-N-B alternatively represents cyclic amines, for example morpholine or piperazine,
- D-T is a direct bond or else
- T is a sym-triazine substituted in position 2 by X3, where X3 has any of the meanings of X1, and
- D is an alkylenediamino bridge of the general formulae 3, 4, 5 and 6:
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- where
- n, m, o and p are each 1-8,
- q is selected from the group consisting of zero and one,
- R7, R8, and R9 are independently C1-C4alkyl, and
- R10 is hydrogen or SO3M.
The process for preparing the inventive dye mixture by mechanically mixing the individual components in solid or liquid form in the requisite proportions.
A process for preparing the inventive dye mixture, which comprises reacting a 2,4,6-trihalotriazine, especially 2,4,6-trichloro- or 2,4,6-trifluoro-triazine, first in a conventional manner with 1-amino-8-naphthol-3,6-disulfonic acid and then with a diazonium salt prepared in a well-known manner from an amine of the general formula (3A) or (3B)
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- where R1, R2. R3, R4, Y1 and Y2 are each as defined above, then reacting the reaction product from the reaction with a diazotized amine of the formula (3A) by reaction with one or more amino compounds of the general formula A-NH-B, where A and B are each as defined above, or to prepare the component of the general formula (2) introducing the fragment D-T in a known manner in the reaction product from the reaction with a diazotized amino compound of the formula (3B), then reacting this reaction product with an amine of the general formula (3C)
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- in a conventional manner and coupling with the diazonium salt of the amines of the general formula (3D) in a known manner to form the bisazo dye.
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Dependencies are inferred from the claim text.