Novel asymmetric phosphine ligand
AssigneeTakasago International Corporation
InventorsKazuhiko Matsumura, Takao Saito
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AssigneeTakasago International Corporation
InventorsKazuhiko Matsumura, Takao Saito
Estimating the term…
A novel phosphine compound having excellent properties (chemical selectivity, enantioselectivity, catalytic activity) as a catalyst for asymmetric syntheses, especially asymmetric hydrogenation. A phosphine-phosphorane compound represented by the following general formula: 1 (wherein R1 represents hydrogen atom or a linear or branched alkyl group having 1 to 4 carbon atoms, R2, R3, R4, and R5 are the same or different, and each represents hydrogen atom, or an alkyl group having 1 to 6 carbon atoms, etc., and each of R2 and R3, R3 and R4, and R4 and R5 may be together combined to form a ring which may contain one or more (preferably 1 to 2) oxygen atoms, and R6 and R7 are the same or different, and each represents a linear or branched alkyl group having 1 to 6 carbon atoms, etc.).
A phosphine-phosphorane compound represented by the general formula (1):
A tertiary phosphine-primary phosphine compound represented by the general formula (2):
Dependencies are inferred from the claim text.